电致发光金属催化合成简单脂肪族羧酸烷基腈

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2024-07-03 DOI:10.3762/bjoc.20.133

Yukang Wang, Yan Yao, Niankai Fu

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引用次数: 0

摘要

摘要我们报告了一种实用且可持续的电光化学金属催化简单脂肪族羧酸脱羧氰化协议。这种环境友好型方法具有底物易得、官能团兼容性广的特点，在温和的反应条件下，无需使用化学氧化剂或昂贵的氰化试剂，即可直接将包括伯烷基和叔烷基酸在内的各种脂肪族羧酸转化为合成用途广泛的烷基硝酸。Chem.2024, 20, 1497–1503. doi:10.3762/bjoc.20.133

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Electrophotochemical metal-catalyzed synthesis of alkylnitriles from simple aliphatic carboxylic acids

Abstract

We report a practical and sustainable electrophotochemical metal-catalyzed protocol for decarboxylative cyanation of simple aliphatic carboxylic acids. This environmentally friendly method features easy availability of substrates, broad functional group compatibility, and directly converts a diverse range of aliphatic carboxylic acids including primary and tertiary alkyl acids into synthetically versatile alkylnitriles without using chemical oxidants or costly cyanating reagents under mild reaction conditions.

Beilstein J. Org. Chem. 2024, 20, 1497–1503. doi:10.3762/bjoc.20.133

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.