Yu Li, Guoqing Wang, Yali Guo, Ning Fang, Jingxiang Li, Zheng Li, Junhan Li
{"title":"制备用于水下排水管道修复的卡旦醇基固化剂","authors":"Yu Li, Guoqing Wang, Yali Guo, Ning Fang, Jingxiang Li, Zheng Li, Junhan Li","doi":"10.1515/epoly-2023-0190","DOIUrl":null,"url":null,"abstract":"The underwater curing agents have demonstrated promising potential in various applications, especially in underwater repair engineering, yet have proven considerable challenging. Here, we report a cardanol-based curing agent for epoxy resin that achieves robust adhesion to steel and concrete substrates both in air and underwater. Cardanol, paraformaldehyde, and <jats:italic>m</jats:italic>-phenyldimethylamine are selected as the polymeric monomers to synthesize curing agent by Mannich reaction in the absence of chemical cross-linker agents. The coating is completely cured within 46 ± 1 min in air and 54 ± 2 min under water with an adhesion of 0 or 1 and a hardness of 5H. The impact strength, shear strength, and tensile strength of coating on underwater concrete were 9.58 ± 0.41 kJ·m<jats:sup>−2</jats:sup>, 13.1 ± 0.3, and 10.5 ± 0.2 MPa, respectively, demonstrating exceptional flexibility and mechanical strength as well as favorable hydrophobicity. This work paves the way for the rehabilitation of underwater drainage network for urban infrastructure and water conservancy projects.","PeriodicalId":11806,"journal":{"name":"e-Polymers","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of cardanol-based curing agent for underwater drainage pipeline repairs\",\"authors\":\"Yu Li, Guoqing Wang, Yali Guo, Ning Fang, Jingxiang Li, Zheng Li, Junhan Li\",\"doi\":\"10.1515/epoly-2023-0190\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The underwater curing agents have demonstrated promising potential in various applications, especially in underwater repair engineering, yet have proven considerable challenging. Here, we report a cardanol-based curing agent for epoxy resin that achieves robust adhesion to steel and concrete substrates both in air and underwater. Cardanol, paraformaldehyde, and <jats:italic>m</jats:italic>-phenyldimethylamine are selected as the polymeric monomers to synthesize curing agent by Mannich reaction in the absence of chemical cross-linker agents. The coating is completely cured within 46 ± 1 min in air and 54 ± 2 min under water with an adhesion of 0 or 1 and a hardness of 5H. The impact strength, shear strength, and tensile strength of coating on underwater concrete were 9.58 ± 0.41 kJ·m<jats:sup>−2</jats:sup>, 13.1 ± 0.3, and 10.5 ± 0.2 MPa, respectively, demonstrating exceptional flexibility and mechanical strength as well as favorable hydrophobicity. This work paves the way for the rehabilitation of underwater drainage network for urban infrastructure and water conservancy projects.\",\"PeriodicalId\":11806,\"journal\":{\"name\":\"e-Polymers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-06-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"e-Polymers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1515/epoly-2023-0190\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"e-Polymers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1515/epoly-2023-0190","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
Preparation of cardanol-based curing agent for underwater drainage pipeline repairs
The underwater curing agents have demonstrated promising potential in various applications, especially in underwater repair engineering, yet have proven considerable challenging. Here, we report a cardanol-based curing agent for epoxy resin that achieves robust adhesion to steel and concrete substrates both in air and underwater. Cardanol, paraformaldehyde, and m-phenyldimethylamine are selected as the polymeric monomers to synthesize curing agent by Mannich reaction in the absence of chemical cross-linker agents. The coating is completely cured within 46 ± 1 min in air and 54 ± 2 min under water with an adhesion of 0 or 1 and a hardness of 5H. The impact strength, shear strength, and tensile strength of coating on underwater concrete were 9.58 ± 0.41 kJ·m−2, 13.1 ± 0.3, and 10.5 ± 0.2 MPa, respectively, demonstrating exceptional flexibility and mechanical strength as well as favorable hydrophobicity. This work paves the way for the rehabilitation of underwater drainage network for urban infrastructure and water conservancy projects.
期刊介绍:
e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome.
The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.