M. Sadegh Ramezani, Sadegh Safaei, Zahra Goodarzi, Mahsa Moradi
{"title":"通过改进制备方法合成并提高宝瓶宁共价有机框架的结晶度,并将其用作合成烯胺酮的绿色无金属催化剂","authors":"M. Sadegh Ramezani, Sadegh Safaei, Zahra Goodarzi, Mahsa Moradi","doi":"10.1007/s10562-024-04770-3","DOIUrl":null,"url":null,"abstract":"<div><p>Herein, a modified synthesis method was presented and the effect of using an aqueous acetic acid solution in the process of synthesizing SQCOF was investigated. Adding a catalytic amount of aqueous solution of acetic acid as a co-catalyst has contributed to improving the quality of crystallinity. Effective parameters in the synthesis of SQCOF, including the concentration and volume of the co-catalyst and reaction solvent, were optimized. Then, the prepared SQCOF was used as a metal-free catalyst with Brønsted acid groups in the condensation reaction between 1,3-dicarbonyl compounds and primary amines. SQCOF was used under solvent-free conditions for the synthesis of enaminones at ambient temperature by mild manual grinding with a mortar and pestle and showed excellent catalytic performance in the above reaction. High performance and efficiency (62 to 96%), high TOF (833 to 1283 h<sup>−1</sup>), short reaction time, easy operation, minimizing the consumption of toxic organic solvents, absence of heavy metals in the framework and green conditions are the main advantages of this study. Also, SQCOF shows good chemical stability and recyclability (7 runs) and acts as an efficient catalyst in the synthesis of <i>β</i>-enaminones.</p><h3>Graphical Abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":508,"journal":{"name":"Catalysis Letters","volume":null,"pages":null},"PeriodicalIF":2.3000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Improving the Crystallinity of a Squaranine Covalent Organic Framework by Modifying the Preparation Method and Using it as a Green and Metal-Free Catalyst for the Synthesis of Enaminone\",\"authors\":\"M. Sadegh Ramezani, Sadegh Safaei, Zahra Goodarzi, Mahsa Moradi\",\"doi\":\"10.1007/s10562-024-04770-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Herein, a modified synthesis method was presented and the effect of using an aqueous acetic acid solution in the process of synthesizing SQCOF was investigated. Adding a catalytic amount of aqueous solution of acetic acid as a co-catalyst has contributed to improving the quality of crystallinity. Effective parameters in the synthesis of SQCOF, including the concentration and volume of the co-catalyst and reaction solvent, were optimized. Then, the prepared SQCOF was used as a metal-free catalyst with Brønsted acid groups in the condensation reaction between 1,3-dicarbonyl compounds and primary amines. SQCOF was used under solvent-free conditions for the synthesis of enaminones at ambient temperature by mild manual grinding with a mortar and pestle and showed excellent catalytic performance in the above reaction. High performance and efficiency (62 to 96%), high TOF (833 to 1283 h<sup>−1</sup>), short reaction time, easy operation, minimizing the consumption of toxic organic solvents, absence of heavy metals in the framework and green conditions are the main advantages of this study. Also, SQCOF shows good chemical stability and recyclability (7 runs) and acts as an efficient catalyst in the synthesis of <i>β</i>-enaminones.</p><h3>Graphical Abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":508,\"journal\":{\"name\":\"Catalysis Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysis Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10562-024-04770-3\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Letters","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10562-024-04770-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Synthesis and Improving the Crystallinity of a Squaranine Covalent Organic Framework by Modifying the Preparation Method and Using it as a Green and Metal-Free Catalyst for the Synthesis of Enaminone
Herein, a modified synthesis method was presented and the effect of using an aqueous acetic acid solution in the process of synthesizing SQCOF was investigated. Adding a catalytic amount of aqueous solution of acetic acid as a co-catalyst has contributed to improving the quality of crystallinity. Effective parameters in the synthesis of SQCOF, including the concentration and volume of the co-catalyst and reaction solvent, were optimized. Then, the prepared SQCOF was used as a metal-free catalyst with Brønsted acid groups in the condensation reaction between 1,3-dicarbonyl compounds and primary amines. SQCOF was used under solvent-free conditions for the synthesis of enaminones at ambient temperature by mild manual grinding with a mortar and pestle and showed excellent catalytic performance in the above reaction. High performance and efficiency (62 to 96%), high TOF (833 to 1283 h−1), short reaction time, easy operation, minimizing the consumption of toxic organic solvents, absence of heavy metals in the framework and green conditions are the main advantages of this study. Also, SQCOF shows good chemical stability and recyclability (7 runs) and acts as an efficient catalyst in the synthesis of β-enaminones.
期刊介绍:
Catalysis Letters aim is the rapid publication of outstanding and high-impact original research articles in catalysis. The scope of the journal covers a broad range of topics in all fields of both applied and theoretical catalysis, including heterogeneous, homogeneous and biocatalysis.
The high-quality original research articles published in Catalysis Letters are subject to rigorous peer review. Accepted papers are published online first and subsequently in print issues. All contributions must include a graphical abstract. Manuscripts should be written in English and the responsibility lies with the authors to ensure that they are grammatically and linguistically correct. Authors for whom English is not the working language are encouraged to consider using a professional language-editing service before submitting their manuscripts.