基于聚乙烯亚胺、聚乙二醇和 Alpha-Cyclodextrin 共聚物的新型聚异构烷烃

IF 1 4区化学 Q4 POLYMER SCIENCE

Polymer Science, Series B Pub Date : 2024-07-02 DOI:10.1134/S1560090424600499

M. P. Kurlykin, M. A. Golovina, M. M. Dudkina, A. V. Ten’kovtsev

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引用次数: 0

摘要

摘要提出了一种从聚乙烯亚胺-块状-聚（乙二醇）-块状-聚乙烯亚胺共聚物和α-环糊精合成聚假紫杉烷的新方法。研究表明，聚假紫杉烷游离氨基的酰化作用可有效阻止复合物在溶液中的分解。通过 1Н 和 13С NMR 光谱、红外分析和 GPC 对合成共聚物的结构进行了详细研究。据推测，所生成的轮烷之所以具有异常高的光学活性，可能与手性螺旋超分子结构的形成有关。

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Novel Type Polyrotaxanes Based on the Copolymer of Polyethylenimine, Poly(ethylene glycol), and Alpha-Cyclodextrin

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Novel Type Polyrotaxanes Based on the Copolymer of Polyethylenimine, Poly(ethylene glycol), and Alpha-Cyclodextrin

A new approach to the synthesis of polyrotaxanes from the polyethylenimine‒block‒poly(ethylene glycol)‒block‒polyethylenimine copolymer and alpha-cyclodextrin has been proposed. It has been shown that the acylation of free amino groups of polypseudorotaxane effectively blocks decomposition of the complex in solution. The structure of the synthesized copolymers has been studied in detail by ¹Н and ¹³С NMR spectroscopy, IR analysis, and GPC. It is assumed that the observed abnormally high optical activity of the resulting rotaxanes is probably associated with the formation of chiral helical supramolecular structures.

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来源期刊

Polymer Science, Series B 化学-高分子科学

CiteScore

1.80

自引率

8.30%

发文量

审稿时长

>0 weeks

期刊介绍： Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed