{"title":"由二羧酸噻吩和 4-咪唑-1-基吡啶混合配体衍生的两种镉（II）化合物的溶剂控制结构变化","authors":"","doi":"10.1080/17415993.2024.2355946","DOIUrl":null,"url":null,"abstract":"<div><p>Two solvent-controlled Cd(II) compounds, formulated as {[Cd<sub>2</sub>(Htdc)<sub>4</sub>(<em>µ</em>-imyp)(H<sub>2</sub>O)<sub>4</sub>]} (<strong>1</strong>), [Cd<sub>2</sub>(<em>µ</em><sub>2</sub>-tdc)<sub>2</sub>(<em>µ</em>-imyp)(DMF)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sub>n</sub> (<strong>2</strong>) (H<sub>2</sub>tdc= 2,5-thiophenedicarboxylic acid, imyp = 4-imidazol-1-yl-pyridine and DMF = N,N-dimethylformamide) have been synthesized by reactions of Cd(NO<sub>3</sub>)<sub>2</sub>·4H<sub>2</sub>O and H<sub>2</sub>tdc with imyp in different solvents, respectively. Both compounds were then characterized by single-crystal X-ray diffraction and other physicochemical methods. In <strong>1</strong>, partially deprotonated Htdc<sup>−</sup> anion as terminal ligand and <em>µ</em>-imyp ligand connect Cd<sup>2+</sup> ions to generate a discrete structure. In <strong>2</strong>, completely deprotonated <em>µ</em><sub>2</sub> – tdc<sup>2−</sup> anions and <em>µ</em>-imyp ligand link Cd<sup>2+</sup> ions into a 1D double chain structure. Both compounds display 3D supramolecular structures through hydrogen bonding interactions. The results provided interesting insights into solvent effects on the structural formation of compounds <strong>1</strong> and <strong>2.</strong> In addition, the solid-state photoluminescent properties of compounds <strong>1</strong> and <strong>2</strong> were also investigated.</p></div><div><p>Two solvent-controlled Cd(II) compounds have been synthesized by reactions of Cd(NO<sub>3</sub>)<sub>2</sub>·4H<sub>2</sub>O and 2,5-thiophenedicarboxylic acid with 4-imidazol-1-yl-pyridine in the different solvents. One compound is a discrete structure, while the other compound has a 1D double chain structure. The results provided interesting insights into solvent effects on the structural formation of compounds.</p></div>","PeriodicalId":17081,"journal":{"name":"Journal of Sulfur Chemistry","volume":"45 4","pages":"Pages 500-510"},"PeriodicalIF":2.1000,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Solvent-controlled structural variation of two Cd(II) compounds derived from thiophene dicarboxylate and 4-imidazol-1-yl-pyridine mixed ligands\",\"authors\":\"\",\"doi\":\"10.1080/17415993.2024.2355946\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Two solvent-controlled Cd(II) compounds, formulated as {[Cd<sub>2</sub>(Htdc)<sub>4</sub>(<em>µ</em>-imyp)(H<sub>2</sub>O)<sub>4</sub>]} (<strong>1</strong>), [Cd<sub>2</sub>(<em>µ</em><sub>2</sub>-tdc)<sub>2</sub>(<em>µ</em>-imyp)(DMF)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]<sub>n</sub> (<strong>2</strong>) (H<sub>2</sub>tdc= 2,5-thiophenedicarboxylic acid, imyp = 4-imidazol-1-yl-pyridine and DMF = N,N-dimethylformamide) have been synthesized by reactions of Cd(NO<sub>3</sub>)<sub>2</sub>·4H<sub>2</sub>O and H<sub>2</sub>tdc with imyp in different solvents, respectively. Both compounds were then characterized by single-crystal X-ray diffraction and other physicochemical methods. In <strong>1</strong>, partially deprotonated Htdc<sup>−</sup> anion as terminal ligand and <em>µ</em>-imyp ligand connect Cd<sup>2+</sup> ions to generate a discrete structure. In <strong>2</strong>, completely deprotonated <em>µ</em><sub>2</sub> – tdc<sup>2−</sup> anions and <em>µ</em>-imyp ligand link Cd<sup>2+</sup> ions into a 1D double chain structure. Both compounds display 3D supramolecular structures through hydrogen bonding interactions. The results provided interesting insights into solvent effects on the structural formation of compounds <strong>1</strong> and <strong>2.</strong> In addition, the solid-state photoluminescent properties of compounds <strong>1</strong> and <strong>2</strong> were also investigated.</p></div><div><p>Two solvent-controlled Cd(II) compounds have been synthesized by reactions of Cd(NO<sub>3</sub>)<sub>2</sub>·4H<sub>2</sub>O and 2,5-thiophenedicarboxylic acid with 4-imidazol-1-yl-pyridine in the different solvents. One compound is a discrete structure, while the other compound has a 1D double chain structure. The results provided interesting insights into solvent effects on the structural formation of compounds.</p></div>\",\"PeriodicalId\":17081,\"journal\":{\"name\":\"Journal of Sulfur Chemistry\",\"volume\":\"45 4\",\"pages\":\"Pages 500-510\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-07-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Sulfur Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1741599324000151\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Sulfur Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1741599324000151","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Solvent-controlled structural variation of two Cd(II) compounds derived from thiophene dicarboxylate and 4-imidazol-1-yl-pyridine mixed ligands
Two solvent-controlled Cd(II) compounds, formulated as {[Cd2(Htdc)4(µ-imyp)(H2O)4]} (1), [Cd2(µ2-tdc)2(µ-imyp)(DMF)2(H2O)2]n (2) (H2tdc= 2,5-thiophenedicarboxylic acid, imyp = 4-imidazol-1-yl-pyridine and DMF = N,N-dimethylformamide) have been synthesized by reactions of Cd(NO3)2·4H2O and H2tdc with imyp in different solvents, respectively. Both compounds were then characterized by single-crystal X-ray diffraction and other physicochemical methods. In 1, partially deprotonated Htdc− anion as terminal ligand and µ-imyp ligand connect Cd2+ ions to generate a discrete structure. In 2, completely deprotonated µ2 – tdc2− anions and µ-imyp ligand link Cd2+ ions into a 1D double chain structure. Both compounds display 3D supramolecular structures through hydrogen bonding interactions. The results provided interesting insights into solvent effects on the structural formation of compounds 1 and 2. In addition, the solid-state photoluminescent properties of compounds 1 and 2 were also investigated.
Two solvent-controlled Cd(II) compounds have been synthesized by reactions of Cd(NO3)2·4H2O and 2,5-thiophenedicarboxylic acid with 4-imidazol-1-yl-pyridine in the different solvents. One compound is a discrete structure, while the other compound has a 1D double chain structure. The results provided interesting insights into solvent effects on the structural formation of compounds.
期刊介绍：
The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science.
Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.
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