{"title":"使用含锆阴离子交换树脂作为氧化树脂吸附水溶液中的碘化物:批处理和柱研究","authors":"Mona Akbari, Shahram Sharifnia","doi":"10.1007/s13738-024-03014-w","DOIUrl":null,"url":null,"abstract":"<div><p>In the current study, a zirconium-containing anion exchange resin was synthesized as an oxidizing resin for iodide adsorption from aqueous solutions. The static adsorption capacity of the oxidizing resin was 612.86 mg/g (obtained from isotherm studies and the Langmuir model). This capacity was 31% higher than the capacity of counter parent resin for iodide adsorption. Adsorption performance of the oxidizing resin was close to maximal over a wide range of pHs (2–7), and the best results were obtained at pH = 3 (8.5% higher than the resin capacity in neutral pH). Iodide removal selectivity in the presence of three commonly encountered anions <span>\\({{\\text{SO}}}_{4}^{2-}\\)</span>, <span>\\({{\\text{NO}}}_{3}^{-}\\)</span> and <span>\\({{\\text{Cl}}}^{-}\\)</span> was improved. The iodide selectivity of oxidizing resin in the presence of <span>\\({{\\text{Cl}}}^{-}\\)</span> ion was excellent. Breakthrough curves of both resins with and without encountered anions were fitted with common breakthrough curve models. The results were consistent with the results of the batch mood experiments. Pseudo-second-order kinetic was described kinetic behavior of both resins well. An iodide adsorption mechanism was proposed using the results of batch experiments and the resin characterizations (XPS and Raman spectra). The potential of oxidizing resin for iodide oxidation into iodine increased the capacity and selectivity of resin toward iodide ions.</p></div>","PeriodicalId":676,"journal":{"name":"Journal of the Iranian Chemical Society","volume":null,"pages":null},"PeriodicalIF":2.2000,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Iodide adsorption from aqueous solutions using zirconium-containing anion exchange resin as an oxidizing resin: batch and column studies\",\"authors\":\"Mona Akbari, Shahram Sharifnia\",\"doi\":\"10.1007/s13738-024-03014-w\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In the current study, a zirconium-containing anion exchange resin was synthesized as an oxidizing resin for iodide adsorption from aqueous solutions. The static adsorption capacity of the oxidizing resin was 612.86 mg/g (obtained from isotherm studies and the Langmuir model). This capacity was 31% higher than the capacity of counter parent resin for iodide adsorption. Adsorption performance of the oxidizing resin was close to maximal over a wide range of pHs (2–7), and the best results were obtained at pH = 3 (8.5% higher than the resin capacity in neutral pH). Iodide removal selectivity in the presence of three commonly encountered anions <span>\\\\({{\\\\text{SO}}}_{4}^{2-}\\\\)</span>, <span>\\\\({{\\\\text{NO}}}_{3}^{-}\\\\)</span> and <span>\\\\({{\\\\text{Cl}}}^{-}\\\\)</span> was improved. The iodide selectivity of oxidizing resin in the presence of <span>\\\\({{\\\\text{Cl}}}^{-}\\\\)</span> ion was excellent. Breakthrough curves of both resins with and without encountered anions were fitted with common breakthrough curve models. The results were consistent with the results of the batch mood experiments. Pseudo-second-order kinetic was described kinetic behavior of both resins well. An iodide adsorption mechanism was proposed using the results of batch experiments and the resin characterizations (XPS and Raman spectra). The potential of oxidizing resin for iodide oxidation into iodine increased the capacity and selectivity of resin toward iodide ions.</p></div>\",\"PeriodicalId\":676,\"journal\":{\"name\":\"Journal of the Iranian Chemical Society\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-06-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Iranian Chemical Society\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s13738-024-03014-w\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Iranian Chemical Society","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s13738-024-03014-w","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Iodide adsorption from aqueous solutions using zirconium-containing anion exchange resin as an oxidizing resin: batch and column studies
In the current study, a zirconium-containing anion exchange resin was synthesized as an oxidizing resin for iodide adsorption from aqueous solutions. The static adsorption capacity of the oxidizing resin was 612.86 mg/g (obtained from isotherm studies and the Langmuir model). This capacity was 31% higher than the capacity of counter parent resin for iodide adsorption. Adsorption performance of the oxidizing resin was close to maximal over a wide range of pHs (2–7), and the best results were obtained at pH = 3 (8.5% higher than the resin capacity in neutral pH). Iodide removal selectivity in the presence of three commonly encountered anions \({{\text{SO}}}_{4}^{2-}\), \({{\text{NO}}}_{3}^{-}\) and \({{\text{Cl}}}^{-}\) was improved. The iodide selectivity of oxidizing resin in the presence of \({{\text{Cl}}}^{-}\) ion was excellent. Breakthrough curves of both resins with and without encountered anions were fitted with common breakthrough curve models. The results were consistent with the results of the batch mood experiments. Pseudo-second-order kinetic was described kinetic behavior of both resins well. An iodide adsorption mechanism was proposed using the results of batch experiments and the resin characterizations (XPS and Raman spectra). The potential of oxidizing resin for iodide oxidation into iodine increased the capacity and selectivity of resin toward iodide ions.
期刊介绍:
JICS is an international journal covering general fields of chemistry. JICS welcomes high quality original papers in English dealing with experimental, theoretical and applied research related to all branches of chemistry. These include the fields of analytical, inorganic, organic and physical chemistry as well as the chemical biology area. Review articles discussing specific areas of chemistry of current chemical or biological importance are also published. JICS ensures visibility of your research results to a worldwide audience in science. You are kindly invited to submit your manuscript to the Editor-in-Chief or Regional Editor. All contributions in the form of original papers or short communications will be peer reviewed and published free of charge after acceptance.