释放金属有机框架的潜力:关于合成、表征和多方面应用的综述

IF 3.9 3区 化学 Q2 POLYMER SCIENCE
Suman Thakur, Sharda Bharti
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引用次数: 0

摘要

过去二十年间,金属有机框架(MOFs)在科学界迅速发展。这类晶体材料具有活性碳和沸石等其他多孔材料所不具备的高度结构和功能可调性。许多 MOF 因其较大的表面积、巨大的孔径、结晶结构和可调性,已被证明是各行各业的可行选择。由于其结构模块化(如使用不同金属、合成后修饰、网状化学等)和特别可控的孔隙率,MOFs 是解决能源和环境可持续性等许多长期社会问题的理想候选材料。MOFs 在许多应用领域都是不可或缺的,尤其是在去除废水中的污染物和新出现的微污染物方面。MOFs 通过催化各种反应来提高吸附能力、传感、给药和水消毒,从而实现了广泛的多方面应用,在多个领域做出了重大贡献。本综述重点介绍 MOF 的基础知识、分类和结构特征、类型、各种合成方法、表征、影响因素以及 MOF 及其纳米复合材料在药物输送、催化、吸附、生物传感和杀灭/灭活真菌、细菌和病毒等多种微生物方面的广泛应用。总之,了解 MOF 合成,包括绿色合成、表征、影响参数和应用,对于利用其特殊品质和扩大其在各行各业的应用,最终创造性地解决紧迫的全球问题至关重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Unlocking the Potential of Metal–Organic Frameworks: A Review on Synthesis, Characterization, and Multifaceted Applications

Unlocking the Potential of Metal–Organic Frameworks: A Review on Synthesis, Characterization, and Multifaceted Applications

Metal–organic frameworks (MOFs) have seen rapid expansion in the scientific community during the last two decades. This type of crystalline material has a great degree of structural and functional tunability not found in other porous materials such as activated carbons, and zeolites. Numerous MOFs have demonstrated themselves to be viable options in a variety of sectors due to their larger surface area, enormous pore size, crystalline structure, and tunability. MOFs are ideal candidate materials to resolve many everlasting societal issues about energy and environmental sustainability and beyond due to their structural modularity (e.g., use of different metals, post-synthetic modifications, reticular chemistry, etc.) and exceptionally controlled porosity. MOFs are indispensable across numerous applications, particularly in the removal of contaminants and emerging micropollutants from wastewater. MOFs enable a wide range of multifaceted applications by catalyzing various reactions for increasing adsorption capacity, sensing, drug delivery, and water disinfection, and thus making major contributions in several fields. This review focuses on the basics of MOFs, their classification and structural features, types, various synthetic methods, characterization, factors affecting and the applications of MOF and its nanocomposites towards a wide range of applications including, drug delivery, catalysis, adsorption, biosensing and killing/inactivation of a wide range of microorganisms including fungi, bacteria, and viruses. In conclusion, knowing MOF synthesis including green synthesis, characterization, influencing parameters, and applications is essential to capitalizing on their special qualities and expanding its application across a range of industries, ultimately resulting in creative responses to urgent global issues.

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来源期刊
CiteScore
8.30
自引率
7.50%
发文量
335
审稿时长
1.8 months
期刊介绍: Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.
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