{"title":"填料床反应器中天然可回收锰矿的烟气脱硫及其随机孔模型的性能预测","authors":"M.S. Parandin, H. Ale Ebrahim, H.R. Norouzi","doi":"10.1016/j.jiec.2024.06.034","DOIUrl":null,"url":null,"abstract":"Various grades of manganese dioxide ores, as a natural recyclable sorbent, can be used in dry flue gas desulfurization (FGD) at moderate temperatures (350–450 °C). This research provided low- and high-grade manganese dioxide ores to examine SO removal in a packed bed reactor. To obtain characteristic parameters of mineral sorbents, XRD, XRF, BET, and mercury porosimetry were employed. Then, kinetic parameters of desulfurization reaction were determined using thermogravimeter analyzer (TGA) and random pore model (RPM) for a single pellet. In desulfurization experiments of simulated flue gas in a packed bed reactor and mass spectrometer (MS) apparatus, the breakthrough times were measured under various operating conditions. The onset of these breakthrough times or life-time of MnO reactor for the SO removal was predicted successfully by RPM for a packed bed reactor using related kinetic constants from TGA. In addition, reacted sorbets were recycled multiple times after washing with water. Not only does this simple method separate MnSO from unreacted sorbents as a valuable byproduct to reduce the FGD cost, but it also improves pore size distribution (PSD) of mineral MnO by creating large pores. Modified PSD of this recycled sorbent caused increased breakthrough time.","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"87 1","pages":""},"PeriodicalIF":5.9000,"publicationDate":"2024-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flue gas desulfurization by natural recyclable manganese ore in packed bed reactor and its performance prediction by random pore model\",\"authors\":\"M.S. Parandin, H. Ale Ebrahim, H.R. Norouzi\",\"doi\":\"10.1016/j.jiec.2024.06.034\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Various grades of manganese dioxide ores, as a natural recyclable sorbent, can be used in dry flue gas desulfurization (FGD) at moderate temperatures (350–450 °C). This research provided low- and high-grade manganese dioxide ores to examine SO removal in a packed bed reactor. To obtain characteristic parameters of mineral sorbents, XRD, XRF, BET, and mercury porosimetry were employed. Then, kinetic parameters of desulfurization reaction were determined using thermogravimeter analyzer (TGA) and random pore model (RPM) for a single pellet. In desulfurization experiments of simulated flue gas in a packed bed reactor and mass spectrometer (MS) apparatus, the breakthrough times were measured under various operating conditions. The onset of these breakthrough times or life-time of MnO reactor for the SO removal was predicted successfully by RPM for a packed bed reactor using related kinetic constants from TGA. In addition, reacted sorbets were recycled multiple times after washing with water. Not only does this simple method separate MnSO from unreacted sorbents as a valuable byproduct to reduce the FGD cost, but it also improves pore size distribution (PSD) of mineral MnO by creating large pores. Modified PSD of this recycled sorbent caused increased breakthrough time.\",\"PeriodicalId\":363,\"journal\":{\"name\":\"Journal of Industrial and Engineering Chemistry\",\"volume\":\"87 1\",\"pages\":\"\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2024-06-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Industrial and Engineering Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jiec.2024.06.034\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Industrial and Engineering Chemistry","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1016/j.jiec.2024.06.034","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Flue gas desulfurization by natural recyclable manganese ore in packed bed reactor and its performance prediction by random pore model
Various grades of manganese dioxide ores, as a natural recyclable sorbent, can be used in dry flue gas desulfurization (FGD) at moderate temperatures (350–450 °C). This research provided low- and high-grade manganese dioxide ores to examine SO removal in a packed bed reactor. To obtain characteristic parameters of mineral sorbents, XRD, XRF, BET, and mercury porosimetry were employed. Then, kinetic parameters of desulfurization reaction were determined using thermogravimeter analyzer (TGA) and random pore model (RPM) for a single pellet. In desulfurization experiments of simulated flue gas in a packed bed reactor and mass spectrometer (MS) apparatus, the breakthrough times were measured under various operating conditions. The onset of these breakthrough times or life-time of MnO reactor for the SO removal was predicted successfully by RPM for a packed bed reactor using related kinetic constants from TGA. In addition, reacted sorbets were recycled multiple times after washing with water. Not only does this simple method separate MnSO from unreacted sorbents as a valuable byproduct to reduce the FGD cost, but it also improves pore size distribution (PSD) of mineral MnO by creating large pores. Modified PSD of this recycled sorbent caused increased breakthrough time.
期刊介绍:
Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.