Gagan Kumar Sharma, Atin Pramanik, Anand B. Puthirath, Shreyasi Chattopadhyay, Tanguy Terlier, Tymofii Pieshkov, Sreehari K. Saju, Robert Vajtai, Davinder Kaur, Pulickel M. Ajayan
{"title":"灵活的镍离子超级电容器/电池混合装置","authors":"Gagan Kumar Sharma, Atin Pramanik, Anand B. Puthirath, Shreyasi Chattopadhyay, Tanguy Terlier, Tymofii Pieshkov, Sreehari K. Saju, Robert Vajtai, Davinder Kaur, Pulickel M. Ajayan","doi":"10.1002/adsu.202400327","DOIUrl":null,"url":null,"abstract":"<p>A hybrid supercapacitor/battery device is proposed by integrating Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3</sub> and multi-walled carbon nanotubes as the battery electrode and carbon nanofiber as a supercapacitor electrode. The device made via the slurry casting of electrode material on foldable thin nickel foils leads to a robust, mechanically flexible sodium-ion capacitor/battery (supercapattery) as a hybrid energy storage system. The device exhibits a specific capacitance of 136 F g<sup>−1</sup> with a corresponding specific capacity of 95 C g<sup>−1</sup> at a potential scan rate of 1 mV s<sup>−1</sup>, a maximum working voltage of 0.70 V, and a power density of 15 kW kg<sup>−1</sup> at 2.50 Wh kg<sup>−1</sup>. Mechanical flexibility tests show practically unperturbed electrochemical properties at significant bending angles of up to 160°, indicating excellent robustness during large-scale device deformation. The current study offers new avenues to develop energy storage systems for next-generation portable and wearable energy storage devices that can be integrated into a variety of platforms.</p>","PeriodicalId":7294,"journal":{"name":"Advanced Sustainable Systems","volume":"8 11","pages":""},"PeriodicalIF":6.5000,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Flexible Na-Ion Supercapacitor/Battery Hybrid Device\",\"authors\":\"Gagan Kumar Sharma, Atin Pramanik, Anand B. Puthirath, Shreyasi Chattopadhyay, Tanguy Terlier, Tymofii Pieshkov, Sreehari K. Saju, Robert Vajtai, Davinder Kaur, Pulickel M. Ajayan\",\"doi\":\"10.1002/adsu.202400327\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A hybrid supercapacitor/battery device is proposed by integrating Na<sub>3</sub>V<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub>F<sub>3</sub> and multi-walled carbon nanotubes as the battery electrode and carbon nanofiber as a supercapacitor electrode. The device made via the slurry casting of electrode material on foldable thin nickel foils leads to a robust, mechanically flexible sodium-ion capacitor/battery (supercapattery) as a hybrid energy storage system. The device exhibits a specific capacitance of 136 F g<sup>−1</sup> with a corresponding specific capacity of 95 C g<sup>−1</sup> at a potential scan rate of 1 mV s<sup>−1</sup>, a maximum working voltage of 0.70 V, and a power density of 15 kW kg<sup>−1</sup> at 2.50 Wh kg<sup>−1</sup>. Mechanical flexibility tests show practically unperturbed electrochemical properties at significant bending angles of up to 160°, indicating excellent robustness during large-scale device deformation. The current study offers new avenues to develop energy storage systems for next-generation portable and wearable energy storage devices that can be integrated into a variety of platforms.</p>\",\"PeriodicalId\":7294,\"journal\":{\"name\":\"Advanced Sustainable Systems\",\"volume\":\"8 11\",\"pages\":\"\"},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-06-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advanced Sustainable Systems\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400327\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Sustainable Systems","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/adsu.202400327","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY","Score":null,"Total":0}
A Flexible Na-Ion Supercapacitor/Battery Hybrid Device
A hybrid supercapacitor/battery device is proposed by integrating Na3V2(PO4)2F3 and multi-walled carbon nanotubes as the battery electrode and carbon nanofiber as a supercapacitor electrode. The device made via the slurry casting of electrode material on foldable thin nickel foils leads to a robust, mechanically flexible sodium-ion capacitor/battery (supercapattery) as a hybrid energy storage system. The device exhibits a specific capacitance of 136 F g−1 with a corresponding specific capacity of 95 C g−1 at a potential scan rate of 1 mV s−1, a maximum working voltage of 0.70 V, and a power density of 15 kW kg−1 at 2.50 Wh kg−1. Mechanical flexibility tests show practically unperturbed electrochemical properties at significant bending angles of up to 160°, indicating excellent robustness during large-scale device deformation. The current study offers new avenues to develop energy storage systems for next-generation portable and wearable energy storage devices that can be integrated into a variety of platforms.
期刊介绍:
Advanced Sustainable Systems, a part of the esteemed Advanced portfolio, serves as an interdisciplinary sustainability science journal. It focuses on impactful research in the advancement of sustainable, efficient, and less wasteful systems and technologies. Aligned with the UN's Sustainable Development Goals, the journal bridges knowledge gaps between fundamental research, implementation, and policy-making. Covering diverse topics such as climate change, food sustainability, environmental science, renewable energy, water, urban development, and socio-economic challenges, it contributes to the understanding and promotion of sustainable systems.