用 mCPBA 进行金属介导氧化的最新进展

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-06-24 DOI:10.1007/s11243-024-00593-8

Ravi Varala, Surbhi Dhadda, Vittal Seema, Mohammed Amanullah, Mohamed Hussien, Mohammed Mujahid Alam

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引用次数: 0

摘要

在现有的各种过氧化物中，偏氯过苯甲酸（mCPBA）是一种有效的氧化试剂，可用于各种氧化转化，包括重排、不同官能团的氧化以及碳-碳键和碳-异原子键的形成。这篇微型综述旨在强调 mCPBA 在有机合成和催化中的代表性金属辅助贡献所涉及的中间物种的性质、结构和反应活性，以及从 2015 年年中至今该反应的范围、优点和缺点。图表摘要

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Recent advances in metal-mediated oxidations with mCPBA

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Recent advances in metal-mediated oxidations with mCPBA

Among the various peroxides that are available, meta-chloroperbenzoic acid (mCPBA) is an effective oxidizing reagent that is used in a variety of oxidative transformations, including rearrangements, oxidation of different functional groups, and the formation of carbon–carbon and carbon–heteroatom bonds. This mini-review aims to emphasize on properties, structures, and reactivities of intermediate species involved in the representative metal-assisted contributions of mCPBA in organic synthesis and catalysis along with its scope, merits, and demerits of the reaction from mid-2015 to date.

Graphical Abstract

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.