{"title":"由 VO2 和 SnO2 组成的薄膜的制作和光学特性","authors":"Chirag Saharan, Deepak Singhwal, Pawan S. Rana","doi":"10.1134/S1063783423600395","DOIUrl":null,"url":null,"abstract":"<p>As the demand for sustainable energy solutions rises, the development of energy-efficient technologies becomes imperative. Smart windows, incorporating thermochromic materials, emerge as promising contributors to reducing building energy consumption. Vanadium dioxide (VO<sub>2</sub>), known for its thermochromic properties, faces challenges in commercial application due to its limited visible light transmittance. This study addresses these challenges by utilizing quartz as a substrate and depositing VO<sub>2</sub> thin films using radio frequency sputtering. To enhance optical performance, a bilayer structure was created by integrating this single-layer film with SnO<sub>2</sub>. Room-temperature X-ray diffraction confirmed the single-phase growth of VO<sub>2</sub> on quartz, and XRD validated the proper fabrication of films. Ultraviolet-visible spectroscopy at room temperature substantiated the improved transmittance of the SnO<sub>2</sub>/VO<sub>2</sub> bilayer, marking a significant advancement toward more efficient and commercially viable smart windows. This research highlights the potential of SnO<sub>2</sub>-based thin films in mitigating the visible light transmittance limitations of VO<sub>2</sub>, thus opening avenues for advanced smart window applications with enhanced energy-saving capabilities. Additionally, Atomic Force Microscopy (AFM) was employed to compare the roughness of the films, and the impact of reduced roughness on optical transmittance was evaluated. The results contribute to the optimization of smart window technologies for broader sustainable energy applications.</p>","PeriodicalId":731,"journal":{"name":"Physics of the Solid State","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fabrication and Optical Characteristics of Thin Films Comprising VO2 and SnO2\",\"authors\":\"Chirag Saharan, Deepak Singhwal, Pawan S. Rana\",\"doi\":\"10.1134/S1063783423600395\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>As the demand for sustainable energy solutions rises, the development of energy-efficient technologies becomes imperative. Smart windows, incorporating thermochromic materials, emerge as promising contributors to reducing building energy consumption. Vanadium dioxide (VO<sub>2</sub>), known for its thermochromic properties, faces challenges in commercial application due to its limited visible light transmittance. This study addresses these challenges by utilizing quartz as a substrate and depositing VO<sub>2</sub> thin films using radio frequency sputtering. To enhance optical performance, a bilayer structure was created by integrating this single-layer film with SnO<sub>2</sub>. Room-temperature X-ray diffraction confirmed the single-phase growth of VO<sub>2</sub> on quartz, and XRD validated the proper fabrication of films. Ultraviolet-visible spectroscopy at room temperature substantiated the improved transmittance of the SnO<sub>2</sub>/VO<sub>2</sub> bilayer, marking a significant advancement toward more efficient and commercially viable smart windows. This research highlights the potential of SnO<sub>2</sub>-based thin films in mitigating the visible light transmittance limitations of VO<sub>2</sub>, thus opening avenues for advanced smart window applications with enhanced energy-saving capabilities. Additionally, Atomic Force Microscopy (AFM) was employed to compare the roughness of the films, and the impact of reduced roughness on optical transmittance was evaluated. 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引用次数: 0
摘要
摘要 随着对可持续能源解决方案的需求不断增加,开发节能技术势在必行。采用热致变色材料的智能窗户在降低建筑能耗方面大有可为。二氧化钒(VO2)因其热致变色特性而闻名,但由于其有限的可见光透射率,在商业应用中面临挑战。本研究利用石英作为基底,通过射频溅射沉积二氧化钒薄膜,从而解决了这些难题。为了提高光学性能,研究人员将这种单层薄膜与二氧化硫整合在一起,形成了双层结构。室温 X 射线衍射证实了 VO2 在石英上的单相生长,而 X 射线衍射则验证了薄膜的正确制造。室温下的紫外可见光谱证实了二氧化锡/二氧化钛双层膜透光率的提高,标志着在实现更高效、更具商业价值的智能窗户方面取得了重大进展。这项研究凸显了二氧化锡薄膜在缓解 VO2 可见光透过率限制方面的潜力,从而为具有更强节能能力的先进智能窗应用开辟了道路。此外,研究还采用原子力显微镜(AFM)比较了薄膜的粗糙度,并评估了粗糙度降低对透光率的影响。这些结果有助于优化智能窗技术,以实现更广泛的可持续能源应用。
Fabrication and Optical Characteristics of Thin Films Comprising VO2 and SnO2
As the demand for sustainable energy solutions rises, the development of energy-efficient technologies becomes imperative. Smart windows, incorporating thermochromic materials, emerge as promising contributors to reducing building energy consumption. Vanadium dioxide (VO2), known for its thermochromic properties, faces challenges in commercial application due to its limited visible light transmittance. This study addresses these challenges by utilizing quartz as a substrate and depositing VO2 thin films using radio frequency sputtering. To enhance optical performance, a bilayer structure was created by integrating this single-layer film with SnO2. Room-temperature X-ray diffraction confirmed the single-phase growth of VO2 on quartz, and XRD validated the proper fabrication of films. Ultraviolet-visible spectroscopy at room temperature substantiated the improved transmittance of the SnO2/VO2 bilayer, marking a significant advancement toward more efficient and commercially viable smart windows. This research highlights the potential of SnO2-based thin films in mitigating the visible light transmittance limitations of VO2, thus opening avenues for advanced smart window applications with enhanced energy-saving capabilities. Additionally, Atomic Force Microscopy (AFM) was employed to compare the roughness of the films, and the impact of reduced roughness on optical transmittance was evaluated. The results contribute to the optimization of smart window technologies for broader sustainable energy applications.
期刊介绍:
Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.