Victor Toral;Yann Houeix;Denice Gerardo;Isabel Blasco-Pascual;Almudena Rivadeneyra;Francisco J. Romero
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引用次数: 0
摘要
本文全面研究了激光合成石墨烯基材料的合成、表征以及在无创生理监测可穿戴设备中的集成。文章采用不同的技术合成和表征了激光诱导石墨烯(LIG)和激光还原氧化石墨烯(LrGO)材料,分析和比较了它们的结构和化学特性,包括扫描电子显微镜(SEM)、显微拉曼光谱和 X 射线光电子能谱(XPS)。这些材料随后被用于制造温度传感器、微型超级电容器(MSC)和心电图(ECG)电极。特别是,利用 LrGO 电导率的温度依赖性,制造出了灵敏度为 -1.23 k $\Omega \cdot ^\{circ }$ C1 的温度依赖性电阻器,将其封装到聚二甲基硅氧烷(PDMS)中以提高其线性度和抗湿度变化能力,然后用作体温传感器。此外,还利用 LIG 的高多孔结构开发了间充质干细胞和心电图电极,显示出良好的电化学和心电图采集性能。此外,还设计并制造了一种可穿戴设备,将这些基于石墨烯的元件与蓝牙低功耗(BLE)微控制器集成在一块刚柔结合的印刷电路板(PCB)上,从而实现了生理数据与外部监控设备的无线传输。对功耗进行了优化,以延长电池寿命,从而实现长时间连续监测。总之,这项研究证明了将石墨烯基材料集成到实际可穿戴应用中的可行性和有效性。
Graphene-Enabled Wearable for Remote ECG and Body Temperature Monitoring
This article presents a comprehensive study on the synthesis, characterization, and integration of laser-synthetized graphene-based materials in a wearable device for noninvasive physiological monitoring. Laser-induced graphene (LIG) and laser-reduced graphene oxide (LrGO) materials are synthesized and characterized under different techniques to analyze and compare their structural and chemical properties, including scanning electron microscopy (SEM), micro-Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS). These materials are used afterward for the fabrication of temperature sensors, micro-supercapacitors (MSCs), and electrocardiogram (ECG) electrodes. In particular, the temperature dependence of the electrical conductivity of LrGO is exploited for the fabrication of temperature-dependent resistors with a sensitivity of −1.23 k
$\Omega \cdot ^{\circ }$
C1, which are used as body temperature sensors after being encapsulated into polydimethylsiloxane (PDMS) to increase their linearity and immunity to humidity changes. Moreover, both MSCs and ECG electrodes are developed by leveraging the highly porous structure of LIG, demonstrating a good electrochemical and ECG acquisition performance. Furthermore, a wearable device is designed and fabricated integrating these graphene-based components in a rigid-flex printed circuit board (PCB) together with a Bluetooth low energy (BLE) microcontroller, thus enabling the wireless transmission of the physiological data to external monitoring devices. The power consumption has been optimized for extended battery life, allowing continuous monitoring over prolonged periods. Overall, this study demonstrates the feasibility and effectiveness of integrating graphene-based materials into real wearable applications.