Xukun Deng, Yanmei Cheng, Chunhui Du, Junde Zhang, Dandan Liu, Guangming Nie
{"title":"作为高性能混合超级电容器电极材料的三氧化钼/碳纳米管/聚(5-羧基吲哚)(MoO3/MWCNT-COOH/P5ICA)纳米复合材料","authors":"Xukun Deng, Yanmei Cheng, Chunhui Du, Junde Zhang, Dandan Liu, Guangming Nie","doi":"10.1016/j.synthmet.2024.117683","DOIUrl":null,"url":null,"abstract":"<div><p>Molybdenum trioxide/carboxyl functionalized carbon multi-wall nanotubes/poly(5-carboxylindole) (MoO<sub>3</sub>/MWCNT-COOH/P5ICA) ternary composites were prepared as supercapacitor electrodes by hydrothermal and electrochemical polymerization methods. When three materials are composite used as electrodes for supercapacitors, the advantages of each material can be effectively integrated, resulting in low impedance and high capacitance characteristics. After optimizing the electrochemical polymerization time of P5ICA, the maximum specific capacitance of the composite electrode can reach 165.6 mF cm<sup>−2</sup>. The symmetric supercapacitor constructed with composite electrodes demonstrates a maximum specific capacitance of 61.0 mF cm<sup>−2</sup>, and the area specific capacitance can remain 74 % of the original after 1000 charge and discharge cycles. This study provides a feasible scheme for preparing high performance supercapacitor materials.</p></div>","PeriodicalId":22245,"journal":{"name":"Synthetic Metals","volume":"307 ","pages":"Article 117683"},"PeriodicalIF":4.0000,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Molybdenum trioxide/carbon nanotubes/poly (5-carboxylindole) (MoO3/MWCNT-COOH/P5ICA) nanocomposites as an electrode material for high-performance hybrid supercapacitors\",\"authors\":\"Xukun Deng, Yanmei Cheng, Chunhui Du, Junde Zhang, Dandan Liu, Guangming Nie\",\"doi\":\"10.1016/j.synthmet.2024.117683\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Molybdenum trioxide/carboxyl functionalized carbon multi-wall nanotubes/poly(5-carboxylindole) (MoO<sub>3</sub>/MWCNT-COOH/P5ICA) ternary composites were prepared as supercapacitor electrodes by hydrothermal and electrochemical polymerization methods. When three materials are composite used as electrodes for supercapacitors, the advantages of each material can be effectively integrated, resulting in low impedance and high capacitance characteristics. After optimizing the electrochemical polymerization time of P5ICA, the maximum specific capacitance of the composite electrode can reach 165.6 mF cm<sup>−2</sup>. The symmetric supercapacitor constructed with composite electrodes demonstrates a maximum specific capacitance of 61.0 mF cm<sup>−2</sup>, and the area specific capacitance can remain 74 % of the original after 1000 charge and discharge cycles. This study provides a feasible scheme for preparing high performance supercapacitor materials.</p></div>\",\"PeriodicalId\":22245,\"journal\":{\"name\":\"Synthetic Metals\",\"volume\":\"307 \",\"pages\":\"Article 117683\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-06-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthetic Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0379677924001450\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthetic Metals","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0379677924001450","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Molybdenum trioxide/carbon nanotubes/poly (5-carboxylindole) (MoO3/MWCNT-COOH/P5ICA) nanocomposites as an electrode material for high-performance hybrid supercapacitors
Molybdenum trioxide/carboxyl functionalized carbon multi-wall nanotubes/poly(5-carboxylindole) (MoO3/MWCNT-COOH/P5ICA) ternary composites were prepared as supercapacitor electrodes by hydrothermal and electrochemical polymerization methods. When three materials are composite used as electrodes for supercapacitors, the advantages of each material can be effectively integrated, resulting in low impedance and high capacitance characteristics. After optimizing the electrochemical polymerization time of P5ICA, the maximum specific capacitance of the composite electrode can reach 165.6 mF cm−2. The symmetric supercapacitor constructed with composite electrodes demonstrates a maximum specific capacitance of 61.0 mF cm−2, and the area specific capacitance can remain 74 % of the original after 1000 charge and discharge cycles. This study provides a feasible scheme for preparing high performance supercapacitor materials.
期刊介绍:
This journal is an international medium for the rapid publication of original research papers, short communications and subject reviews dealing with research on and applications of electronic polymers and electronic molecular materials including novel carbon architectures. These functional materials have the properties of metals, semiconductors or magnets and are distinguishable from elemental and alloy/binary metals, semiconductors and magnets.