Wenhui Zhu , Hongbao Zhu , Jun Liu , Jintang Zhou , Jiaqi Tao , Kexin Zou , Xuewei Tao , Yiming Lei , Zhengjun Yao , Zhitao Li , Yao Ma , Peijiang Liu , Hexia Huang , Zhong Li
{"title":"用于大规模制备高效电磁波吸收的类 MIL-88B 的室温去质子化工程","authors":"Wenhui Zhu , Hongbao Zhu , Jun Liu , Jintang Zhou , Jiaqi Tao , Kexin Zou , Xuewei Tao , Yiming Lei , Zhengjun Yao , Zhitao Li , Yao Ma , Peijiang Liu , Hexia Huang , Zhong Li","doi":"10.1016/j.carbon.2024.119369","DOIUrl":null,"url":null,"abstract":"<div><p>Metal-organic frameworks (MOFs)-derived electromagnetic functional materials are a hot research trend in the field of microwave absorption (MA). However, there is a lack of high-yield strategies to drive high-performance MOFs-derived MA absorbers out of the laboratory. Herein, we prepared MIL-88B-like using a simple room-temperature liquid-phase method with more than 75 times the yield of the solvothermal method. The obtained MOFs were pyrolyzed to form C/FeO/FeN<sub>0.0324</sub>/Fe quaternary composite materials. Under suitable graphitizing conditions, the moderate conductivity of derivative material of M1 precursor carbonized at 700 °C (M1-700) not only meets the requirement of impedance matching but also provides high conduction loss. Meanwhile, the multiple polarization loss mechanisms from defect-induced polarization, dipole polarization, heterogeneous interfaces, and magnetic loss mechanism synergize with each other, resulting in an effective absorption bandwidth (EAB) of 6.71 GHz and a reflection loss (RL) value of −62.57 dB at 22.5 wt% filler, which is a 6-fold increase in the RL compared with that of the conventional MIL-88B-derived wave absorber. In conclusion, this work provides a feasible solution for practical absorbers and an excellent reference value for high MA performance materials for applications.</p></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5000,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Room temperature deprotonation engineering for large-scale preparation of MIL-88B-like for efficient electromagnetic wave absorption\",\"authors\":\"Wenhui Zhu , Hongbao Zhu , Jun Liu , Jintang Zhou , Jiaqi Tao , Kexin Zou , Xuewei Tao , Yiming Lei , Zhengjun Yao , Zhitao Li , Yao Ma , Peijiang Liu , Hexia Huang , Zhong Li\",\"doi\":\"10.1016/j.carbon.2024.119369\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Metal-organic frameworks (MOFs)-derived electromagnetic functional materials are a hot research trend in the field of microwave absorption (MA). However, there is a lack of high-yield strategies to drive high-performance MOFs-derived MA absorbers out of the laboratory. Herein, we prepared MIL-88B-like using a simple room-temperature liquid-phase method with more than 75 times the yield of the solvothermal method. The obtained MOFs were pyrolyzed to form C/FeO/FeN<sub>0.0324</sub>/Fe quaternary composite materials. Under suitable graphitizing conditions, the moderate conductivity of derivative material of M1 precursor carbonized at 700 °C (M1-700) not only meets the requirement of impedance matching but also provides high conduction loss. Meanwhile, the multiple polarization loss mechanisms from defect-induced polarization, dipole polarization, heterogeneous interfaces, and magnetic loss mechanism synergize with each other, resulting in an effective absorption bandwidth (EAB) of 6.71 GHz and a reflection loss (RL) value of −62.57 dB at 22.5 wt% filler, which is a 6-fold increase in the RL compared with that of the conventional MIL-88B-derived wave absorber. In conclusion, this work provides a feasible solution for practical absorbers and an excellent reference value for high MA performance materials for applications.</p></div>\",\"PeriodicalId\":262,\"journal\":{\"name\":\"Carbon\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.5000,\"publicationDate\":\"2024-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0008622324005888\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0008622324005888","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Room temperature deprotonation engineering for large-scale preparation of MIL-88B-like for efficient electromagnetic wave absorption
Metal-organic frameworks (MOFs)-derived electromagnetic functional materials are a hot research trend in the field of microwave absorption (MA). However, there is a lack of high-yield strategies to drive high-performance MOFs-derived MA absorbers out of the laboratory. Herein, we prepared MIL-88B-like using a simple room-temperature liquid-phase method with more than 75 times the yield of the solvothermal method. The obtained MOFs were pyrolyzed to form C/FeO/FeN0.0324/Fe quaternary composite materials. Under suitable graphitizing conditions, the moderate conductivity of derivative material of M1 precursor carbonized at 700 °C (M1-700) not only meets the requirement of impedance matching but also provides high conduction loss. Meanwhile, the multiple polarization loss mechanisms from defect-induced polarization, dipole polarization, heterogeneous interfaces, and magnetic loss mechanism synergize with each other, resulting in an effective absorption bandwidth (EAB) of 6.71 GHz and a reflection loss (RL) value of −62.57 dB at 22.5 wt% filler, which is a 6-fold increase in the RL compared with that of the conventional MIL-88B-derived wave absorber. In conclusion, this work provides a feasible solution for practical absorbers and an excellent reference value for high MA performance materials for applications.
期刊介绍:
The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.