受酸性矿井排水影响介质中的水文地球化学与硅藻之间的关系:伊比利亚黄铁矿带案例;全金属成矿省的功能模型

IF 3.4 2区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Ana Teresa Luís , Juan Carlos Fortes , María Santisteban , José Miguel Dávila , Manuel A. Caraballo , Juan María Terrones-Saeta , Jesus Diaz-Curiel , José Antonio Grande
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引用次数: 0

摘要

伊比利亚黄铁矿带(IPB)是最重要的金属成矿带之一,蕴藏着块状硫化物,从葡萄牙的 Canal Caveira-Lousal 到西班牙的 Gerena(塞维利亚附近),绵延 230 多公里。该地区仅在西班牙部分就有 88 个活跃和不活跃矿山,在葡萄牙有近 30 个,这些矿山产生的酸性矿井排水(AMD)污染了主要的河流流域:科罗纳河、罗克索河(葡萄牙)、奥迪尔河、廷托河、瓜迪亚马尔河(西班牙)和昌扎-瓜迪亚纳河(葡萄牙/西班牙),并因此污染了 35 个酸性取样点,其中 14 个在葡萄牙,21 个在西班牙。实验室测定了水体的物理化学参数(EC、Eh、pH、Al、As、Cd、Co、Cu、Fe、Mn、Ni、Pb、Zn、SO42-)、酸性硅藻(Pinacid%)和硅藻多样性(N°sps)。然后,将结果整合到一个包含 16 个变量和 35 个采样点的数据库中,通过因子分析和聚类分析进行统计分析。首先,在 35 个采样点中,显示出明显的生态障碍,揭示了如何将距离较远的采样点配对在一起。最后,污染与生物群相互作用模型的制定受两个因素的制约:1-未修复的采矿表面和 2-水框架指令(WFD)超标。扩散图显示,尽管未修复的采矿表面有所增加,但从污染物达到一定浓度开始,盐类开始沉淀:AMD 过程增加,但 WFD 没有增加。科学文献中有许多旨在界定硅藻-水文地质-化学相互关系的著作,但没有一篇涵盖整个冶金矿区的著作,因为冶金矿区可能存在生态障碍,制约着硅藻物种和群体在酸性(pH 值:1.90-4.43)环境中的演化和分布。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Relationships between hydrogeochemistry and diatoms in acid mine drainage affected media: The case of Iberian pyrite belt; functioning models for an all metallogenetic province

Relationships between hydrogeochemistry and diatoms in acid mine drainage affected media: The case of Iberian pyrite belt; functioning models for an all metallogenetic province

The Iberian Pyritic Belt (IPB) is one of the most important metallogenic provinces, which hosts massive sulfides and extends over 230 km from Canal Caveira-Lousal in Portugal to Gerena (near Seville) in Spain. It has 88 active and inactive mines only in the Spanish part and near 30 in Portugal that generate Acid Mine Drainage (AMD) pollution to the main river basins, Corona, Roxo (Portugal), Odiel, Tinto, Guadiamar (Spain) and Chanza-Guadiana (Portugal/Spain) and consequenty to the 35 acidic sampling sites, 14 in Portugal and 21 in Spain, selected for this unique study. The physico-chemical parameters of waters (EC, Eh, pH, Al, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, SO42−), acidic diatoms (%Pinacid) and diatom diversity (N°sps) were determined in the laboratory. Then, the results were integrated in a database with 16 variables and 35 sampling points to be statistically analyzed by factor and cluster analysis. In the first, for the 35 sampling sites, it showed a clear inexistence of ecological barriers, exposing how could distantly sampling points be paired together. The last, allowed the pollution–biota interaction models formulation governed by 2 factors: 1-Unrestored Mining Surfaces and 2-WFD (Water Framework Directive) exceeding limits. Dispersion diagram showed that although the unrestored mining surface increases, starting from a certain concentration of contaminants, salts begin to precipitate: the AMD process increases but the WFD does not. There are numerous works in the scientific literature aimed to define diatom-hydro-geo-chemistry interrelationships, but none that covers an entire metallogenetic province where ecological barriers could exist, conditioning the diatom species and groups evolution and distribution in an acidic (pH: 1.90–4.43) environment.

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来源期刊
Journal of Geochemical Exploration
Journal of Geochemical Exploration 地学-地球化学与地球物理
CiteScore
7.40
自引率
7.70%
发文量
148
审稿时长
8.1 months
期刊介绍: Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics. Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to: define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas. analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation. evaluate effects of historical mining activities on the surface environment. trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices. assess and quantify natural and technogenic radioactivity in the environment. determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis. assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches. Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.
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