Ana Teresa Luís , Juan Carlos Fortes , María Santisteban , José Miguel Dávila , Manuel A. Caraballo , Juan María Terrones-Saeta , Jesus Diaz-Curiel , José Antonio Grande
{"title":"受酸性矿井排水影响介质中的水文地球化学与硅藻之间的关系:伊比利亚黄铁矿带案例;全金属成矿省的功能模型","authors":"Ana Teresa Luís , Juan Carlos Fortes , María Santisteban , José Miguel Dávila , Manuel A. Caraballo , Juan María Terrones-Saeta , Jesus Diaz-Curiel , José Antonio Grande","doi":"10.1016/j.gexplo.2024.107537","DOIUrl":null,"url":null,"abstract":"<div><p>The Iberian Pyritic Belt (IPB) is one of the most important metallogenic provinces, which hosts massive sulfides and extends over 230 km from Canal Caveira-Lousal in Portugal to Gerena (near Seville) in Spain. It has 88 active and inactive mines only in the Spanish part and near 30 in Portugal that generate Acid Mine Drainage (AMD) pollution to the main river basins, Corona, Roxo (Portugal), Odiel, Tinto, Guadiamar (Spain) and Chanza-Guadiana (Portugal/Spain) and consequenty to the 35 acidic sampling sites, 14 in Portugal and 21 in Spain, selected for this unique study. The physico-chemical parameters of waters (EC, Eh, pH, Al, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, SO<sub>4</sub><sup>2−</sup>), acidic diatoms (%Pinacid) and diatom diversity (N°sps) were determined in the laboratory. Then, the results were integrated in a database with 16 variables and 35 sampling points to be statistically analyzed by factor and cluster analysis. In the first, for the 35 sampling sites, it showed a clear inexistence of ecological barriers, exposing how could distantly sampling points be paired together. The last, allowed the pollution–biota interaction models formulation governed by 2 factors: 1-Unrestored Mining Surfaces and 2-WFD (Water Framework Directive) exceeding limits. Dispersion diagram showed that although the unrestored mining surface increases, starting from a certain concentration of contaminants, salts begin to precipitate: the AMD process increases but the WFD does not. There are numerous works in the scientific literature aimed to define diatom-hydro-geo-chemistry interrelationships, but none that covers an entire metallogenetic province where ecological barriers could exist, conditioning the diatom species and groups evolution and distribution in an acidic (pH: 1.90–4.43) environment.</p></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":"264 ","pages":"Article 107537"},"PeriodicalIF":3.4000,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Relationships between hydrogeochemistry and diatoms in acid mine drainage affected media: The case of Iberian pyrite belt; functioning models for an all metallogenetic province\",\"authors\":\"Ana Teresa Luís , Juan Carlos Fortes , María Santisteban , José Miguel Dávila , Manuel A. Caraballo , Juan María Terrones-Saeta , Jesus Diaz-Curiel , José Antonio Grande\",\"doi\":\"10.1016/j.gexplo.2024.107537\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Iberian Pyritic Belt (IPB) is one of the most important metallogenic provinces, which hosts massive sulfides and extends over 230 km from Canal Caveira-Lousal in Portugal to Gerena (near Seville) in Spain. It has 88 active and inactive mines only in the Spanish part and near 30 in Portugal that generate Acid Mine Drainage (AMD) pollution to the main river basins, Corona, Roxo (Portugal), Odiel, Tinto, Guadiamar (Spain) and Chanza-Guadiana (Portugal/Spain) and consequenty to the 35 acidic sampling sites, 14 in Portugal and 21 in Spain, selected for this unique study. The physico-chemical parameters of waters (EC, Eh, pH, Al, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, SO<sub>4</sub><sup>2−</sup>), acidic diatoms (%Pinacid) and diatom diversity (N°sps) were determined in the laboratory. Then, the results were integrated in a database with 16 variables and 35 sampling points to be statistically analyzed by factor and cluster analysis. In the first, for the 35 sampling sites, it showed a clear inexistence of ecological barriers, exposing how could distantly sampling points be paired together. The last, allowed the pollution–biota interaction models formulation governed by 2 factors: 1-Unrestored Mining Surfaces and 2-WFD (Water Framework Directive) exceeding limits. Dispersion diagram showed that although the unrestored mining surface increases, starting from a certain concentration of contaminants, salts begin to precipitate: the AMD process increases but the WFD does not. There are numerous works in the scientific literature aimed to define diatom-hydro-geo-chemistry interrelationships, but none that covers an entire metallogenetic province where ecological barriers could exist, conditioning the diatom species and groups evolution and distribution in an acidic (pH: 1.90–4.43) environment.</p></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":\"264 \",\"pages\":\"Article 107537\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-06-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0375674224001535\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375674224001535","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Relationships between hydrogeochemistry and diatoms in acid mine drainage affected media: The case of Iberian pyrite belt; functioning models for an all metallogenetic province
The Iberian Pyritic Belt (IPB) is one of the most important metallogenic provinces, which hosts massive sulfides and extends over 230 km from Canal Caveira-Lousal in Portugal to Gerena (near Seville) in Spain. It has 88 active and inactive mines only in the Spanish part and near 30 in Portugal that generate Acid Mine Drainage (AMD) pollution to the main river basins, Corona, Roxo (Portugal), Odiel, Tinto, Guadiamar (Spain) and Chanza-Guadiana (Portugal/Spain) and consequenty to the 35 acidic sampling sites, 14 in Portugal and 21 in Spain, selected for this unique study. The physico-chemical parameters of waters (EC, Eh, pH, Al, As, Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn, SO42−), acidic diatoms (%Pinacid) and diatom diversity (N°sps) were determined in the laboratory. Then, the results were integrated in a database with 16 variables and 35 sampling points to be statistically analyzed by factor and cluster analysis. In the first, for the 35 sampling sites, it showed a clear inexistence of ecological barriers, exposing how could distantly sampling points be paired together. The last, allowed the pollution–biota interaction models formulation governed by 2 factors: 1-Unrestored Mining Surfaces and 2-WFD (Water Framework Directive) exceeding limits. Dispersion diagram showed that although the unrestored mining surface increases, starting from a certain concentration of contaminants, salts begin to precipitate: the AMD process increases but the WFD does not. There are numerous works in the scientific literature aimed to define diatom-hydro-geo-chemistry interrelationships, but none that covers an entire metallogenetic province where ecological barriers could exist, conditioning the diatom species and groups evolution and distribution in an acidic (pH: 1.90–4.43) environment.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.