实现正配位反应的激进策略

IF 42.8 1区化学 Q1 CHEMISTRY, PHYSICAL

Nature Catalysis Pub Date : 2024-06-26 DOI:10.1038/s41929-024-01178-5

Quoc Hoang Pham, Rene M. Koenigs

引用次数: 0

摘要

将铁（ii）催化剂和羟基铵盐结合在一起，可将惰性芳香族 C-H 键直接选择性地转化为有价值、无保护的胺官能团。这种方法解决了现代合成中一个长期存在的难题。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A radical strategy towards ortho-amination reactions

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A radical strategy towards ortho-amination reactions

A combination of an iron(ii)-catalyst and a hydroxylammonium salt enables the direct and selective conversion of an inert aromatic C–H bond to a valuable, unprotected amine functionality. This approach solves a long standing challenge in modern synthesis.

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来源期刊

Nature Catalysis Chemical Engineering-Bioengineering

CiteScore

52.10

自引率

1.10%

发文量

140

期刊介绍： Nature Catalysis serves as a platform for researchers across chemistry and related fields, focusing on homogeneous catalysis, heterogeneous catalysis, and biocatalysts, encompassing both fundamental and applied studies. With a particular emphasis on advancing sustainable industries and processes, the journal provides comprehensive coverage of catalysis research, appealing to scientists, engineers, and researchers in academia and industry. Maintaining the high standards of the Nature brand, Nature Catalysis boasts a dedicated team of professional editors, rigorous peer-review processes, and swift publication times, ensuring editorial independence and quality. The journal publishes work spanning heterogeneous catalysis, homogeneous catalysis, and biocatalysis, covering areas such as catalytic synthesis, mechanisms, characterization, computational studies, nanoparticle catalysis, electrocatalysis, photocatalysis, environmental catalysis, asymmetric catalysis, and various forms of organocatalysis.