Tao Yang, Liang Li, Jiahang Zou, Yiqing Yao, Qingan Zhang, Zhipeng Jiang, Yongtao Li
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引用次数: 0
摘要
高能量密度锂金属电池(LMB)在未来的储能系统中具有巨大潜力,但其循环稳定性差,安全性令人担忧,尤其是在高倍率条件下。在电解液中添加含氟溶剂可有效提高锂金属阳极(LMA)的稳定性,并改善 LMB 的安全性。然而,大量引入含氟溶剂不利于锂离子(Li+)的传输,从而对 LMB 的速率性能产生负面影响。在此,我们设计了一种安全的醚电解质(SEE),它既具有高锂离子传导性和不可燃性,又能保持与 LMA 的高度兼容性。使用 SEE 的锂-镍 0.8Mn0.1Co0.1O2 (NMC811) 电池可表现出卓越的电化学性能,在高达 30 C 的速率下可提供 113.1 mAh g-¹ 的放电容量,在 10 C 下循环 300 次后仍能保持 90% 的初始容量。
A Safe Ether Electrolyte Enabling High-Rate Lithium Metal Batteries
High-energy-density lithium metal batteries (LMBs) hold enormous potential for future energy storage systems but are plagued by poor cycling stability and safety concerns, especially under high-rate conditions. The addition of fluorinated solvents to the electrolyte is effective in enhancing the stability of the lithium metal anode (LMA) and improving safety for LMBs. However, the extensive introduction of fluorinated solvents is not conducive to the transport of lithium-ions (Li+), thereby negatively affecting the rate performance of LMBs. Herein, a safe ether electrolyte (SEE) is designed that exhibits both high Li+ conductivity and nonflammability, while maintaining high compatibility with the LMA. Li–LiNi0.8Mn0.1Co0.1O2 (NMC811) cells utilizing SEE can demonstrate remarkable electrochemical performance, delivering a discharge capacity of 113.1 mAh g⁻¹ at rates as high as 30 C and maintaining 90% of their initial capacity over 300 cycles at 10 C. Moreover, a practical Li-NCM811 full cell assembled with SEE achieves stable cycling at 3 C.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
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