Ziqi FENG , Fang HAO , Lin HU , Gaowei HU , Yazhen ZHANG , Yangming LI , Wei WANG , Hao LI , Junjie XIAO , Jinqiang TIAN
{"title":"深部热流体活动下氦的遗传源、迁移和积累:南海莺歌海盆地乐东断陷区案例研究","authors":"Ziqi FENG , Fang HAO , Lin HU , Gaowei HU , Yazhen ZHANG , Yangming LI , Wei WANG , Hao LI , Junjie XIAO , Jinqiang TIAN","doi":"10.1016/S1876-3804(24)60503-3","DOIUrl":null,"url":null,"abstract":"<div><p>Based on the geochemical parameters and analytical data, the heat conservation equation, mass balance law, Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium, and the initial He concentration and thermal driving mechanism of mantle-derived helium, in the Ledong Diapir area, the Yinggehai Basin, in order to understand the genetic source, migration and accumulation mechanisms of helium under deep thermal fluid activities. The average content of mantle-derived He is only 0.001 4%, the <sup>3</sup>He/<sup>4</sup>He value is (0.002–2.190)×10<sup>−6</sup>, and the <em>R</em>/<em>R</em><sub>a</sub> value ranges from 0.01 to 1.52, indicating the contribution of mantle-derived He is 0.09%–19.84%, while the proportion of crust-derived helium can reach over 80%. Quantitative analysis indicates that the crust-derived helium is dominated by external input, followed by in-situ production, in the Ledong diapir area. The crust- derived helium exhibits an in-situ <sup>4</sup>He yield rate of (7.66– 7.95)×10<sup>−13</sup> cm<sup>3</sup>/(a·g), an in-situ <sup>4</sup>He yield of (4.10–4.25)× 10<sup>−4</sup> cm<sup>3</sup>/g, and an external <sup>4</sup>He influx of (5.84–9.06)×10<sup>−2</sup> cm<sup>3</sup>/g. These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions. The ratio of initial mole volume of <sup>3</sup>He to enthalpy (<em>W</em>) is (0.004–0.018) ×10<sup>−11</sup> cm<sup>3</sup>/J, and the heat contribution from the deep mantle (<em>X</em><sub>M</sub>) accounts for 7.63%–36.18%, indicating that deep hot fluid activities drive the migration of mantle-derived <sup>3</sup>He. The primary helium migration depends on advection, while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation. From deep to shallow layers, the CO<sub>2</sub>/<sup>3</sup>He value rises from 1.34×10<sup>9</sup> to 486×10<sup>9</sup>, indicating large amount of CO<sub>2</sub> has escaped. Under the influence of deep thermal fluid, helium migration and accumulation mechanisms include: deep heat driven diffusion, advection release, vertical hydrothermal degassing, shallow lateral migration, accumulation in traps far from faults, partial pressure balance and sealing capability.</p></div>","PeriodicalId":67426,"journal":{"name":"Petroleum Exploration and Development","volume":"51 3","pages":"Pages 753-766"},"PeriodicalIF":7.0000,"publicationDate":"2024-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1876380424605033/pdf?md5=034d7c0aaa0b220d3bc95e08e249321e&pid=1-s2.0-S1876380424605033-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Genetic source, migration and accumulation of helium under deep thermal fluid activities: A case study of Ledong diapir area in Yinggehai Basin, South China Sea\",\"authors\":\"Ziqi FENG , Fang HAO , Lin HU , Gaowei HU , Yazhen ZHANG , Yangming LI , Wei WANG , Hao LI , Junjie XIAO , Jinqiang TIAN\",\"doi\":\"10.1016/S1876-3804(24)60503-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Based on the geochemical parameters and analytical data, the heat conservation equation, mass balance law, Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium, and the initial He concentration and thermal driving mechanism of mantle-derived helium, in the Ledong Diapir area, the Yinggehai Basin, in order to understand the genetic source, migration and accumulation mechanisms of helium under deep thermal fluid activities. The average content of mantle-derived He is only 0.001 4%, the <sup>3</sup>He/<sup>4</sup>He value is (0.002–2.190)×10<sup>−6</sup>, and the <em>R</em>/<em>R</em><sub>a</sub> value ranges from 0.01 to 1.52, indicating the contribution of mantle-derived He is 0.09%–19.84%, while the proportion of crust-derived helium can reach over 80%. Quantitative analysis indicates that the crust-derived helium is dominated by external input, followed by in-situ production, in the Ledong diapir area. The crust- derived helium exhibits an in-situ <sup>4</sup>He yield rate of (7.66– 7.95)×10<sup>−13</sup> cm<sup>3</sup>/(a·g), an in-situ <sup>4</sup>He yield of (4.10–4.25)× 10<sup>−4</sup> cm<sup>3</sup>/g, and an external <sup>4</sup>He influx of (5.84–9.06)×10<sup>−2</sup> cm<sup>3</sup>/g. These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions. The ratio of initial mole volume of <sup>3</sup>He to enthalpy (<em>W</em>) is (0.004–0.018) ×10<sup>−11</sup> cm<sup>3</sup>/J, and the heat contribution from the deep mantle (<em>X</em><sub>M</sub>) accounts for 7.63%–36.18%, indicating that deep hot fluid activities drive the migration of mantle-derived <sup>3</sup>He. The primary helium migration depends on advection, while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation. From deep to shallow layers, the CO<sub>2</sub>/<sup>3</sup>He value rises from 1.34×10<sup>9</sup> to 486×10<sup>9</sup>, indicating large amount of CO<sub>2</sub> has escaped. Under the influence of deep thermal fluid, helium migration and accumulation mechanisms include: deep heat driven diffusion, advection release, vertical hydrothermal degassing, shallow lateral migration, accumulation in traps far from faults, partial pressure balance and sealing capability.</p></div>\",\"PeriodicalId\":67426,\"journal\":{\"name\":\"Petroleum Exploration and Development\",\"volume\":\"51 3\",\"pages\":\"Pages 753-766\"},\"PeriodicalIF\":7.0000,\"publicationDate\":\"2024-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1876380424605033/pdf?md5=034d7c0aaa0b220d3bc95e08e249321e&pid=1-s2.0-S1876380424605033-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Petroleum Exploration and Development\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1876380424605033\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Petroleum Exploration and Development","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1876380424605033","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Genetic source, migration and accumulation of helium under deep thermal fluid activities: A case study of Ledong diapir area in Yinggehai Basin, South China Sea
Based on the geochemical parameters and analytical data, the heat conservation equation, mass balance law, Rayleigh fractionation model and other methods were used to quantify the in-situ yield and external flux of crust-derived helium, and the initial He concentration and thermal driving mechanism of mantle-derived helium, in the Ledong Diapir area, the Yinggehai Basin, in order to understand the genetic source, migration and accumulation mechanisms of helium under deep thermal fluid activities. The average content of mantle-derived He is only 0.001 4%, the 3He/4He value is (0.002–2.190)×10−6, and the R/Ra value ranges from 0.01 to 1.52, indicating the contribution of mantle-derived He is 0.09%–19.84%, while the proportion of crust-derived helium can reach over 80%. Quantitative analysis indicates that the crust-derived helium is dominated by external input, followed by in-situ production, in the Ledong diapir area. The crust- derived helium exhibits an in-situ 4He yield rate of (7.66– 7.95)×10−13 cm3/(a·g), an in-situ 4He yield of (4.10–4.25)× 10−4 cm3/g, and an external 4He influx of (5.84–9.06)×10−2 cm3/g. These results may be related to atmospheric recharge into formation fluid and deep rock-water interactions. The ratio of initial mole volume of 3He to enthalpy (W) is (0.004–0.018) ×10−11 cm3/J, and the heat contribution from the deep mantle (XM) accounts for 7.63%–36.18%, indicating that deep hot fluid activities drive the migration of mantle-derived 3He. The primary helium migration depends on advection, while the secondary migration is controlled by hydrothermal degassing and gas-liquid separation. From deep to shallow layers, the CO2/3He value rises from 1.34×109 to 486×109, indicating large amount of CO2 has escaped. Under the influence of deep thermal fluid, helium migration and accumulation mechanisms include: deep heat driven diffusion, advection release, vertical hydrothermal degassing, shallow lateral migration, accumulation in traps far from faults, partial pressure balance and sealing capability.