Hangyu Li , Minghong Rui , Yuan Li , Sumei Wang , Guodong Xia
{"title":"利用硼氢化钠蚀刻对 CdS/Sb2S3 进行高效界面修饰,以提高低成本全无机锑基太阳能电池的性能","authors":"Hangyu Li , Minghong Rui , Yuan Li , Sumei Wang , Guodong Xia","doi":"10.1016/j.solmat.2024.112991","DOIUrl":null,"url":null,"abstract":"<div><p>Antimony sulfide (Sb<sub>2</sub>S<sub>3</sub>) is a promising material for photovoltaic applications because of its high absorption coefficient, environmental friendliness and low cost. Nevertheless, the conversion efficiency of Sb<sub>2</sub>S<sub>3</sub> solar cells severely deviates from theoretical predictions, and the interface between CdS and Sb<sub>2</sub>S<sub>3</sub> is crucial for the overall performance. In this study, we conducted a highly effective sodium borohydride (NaBH<sub>4</sub>) etching to modify the CdS/Sb<sub>2</sub>S<sub>3</sub> interface, aiming to improve the device performance. The NaBH<sub>4</sub> etching led to a reduction in surface roughness and an enhancement in the hydrophilicity of the CdS layer, creating a more conducive environment for the subsequent deposition of the Sb<sub>2</sub>S<sub>3</sub> absorber layer. Simultaneously, the reduction of cadmium oxide serves to optimize interfacial energy alignment and minimize recombination losses. Ultimately, our full-inorganic Sb<sub>2</sub>S<sub>3</sub> solar cells, featuring the configuration FTO/CdS/Sb<sub>2</sub>S<sub>3</sub>/MnS/Carbon, attain a PCE of 6.26%. This marks a significant improvement of 15% compared to cells without NaBH<sub>4</sub> etching. This study presents a feasible and efficient perspective for modifying the CdS/Sb<sub>2</sub>S<sub>3</sub> interface, thereby enhancing the performance of Sb-based solar cells.</p></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":null,"pages":null},"PeriodicalIF":6.3000,"publicationDate":"2024-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Efficient CdS/Sb2S3 interfacial modification using sodium borohydride etching for enhanced performance of low-cost full-inorganic antimony-based solar cells\",\"authors\":\"Hangyu Li , Minghong Rui , Yuan Li , Sumei Wang , Guodong Xia\",\"doi\":\"10.1016/j.solmat.2024.112991\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Antimony sulfide (Sb<sub>2</sub>S<sub>3</sub>) is a promising material for photovoltaic applications because of its high absorption coefficient, environmental friendliness and low cost. Nevertheless, the conversion efficiency of Sb<sub>2</sub>S<sub>3</sub> solar cells severely deviates from theoretical predictions, and the interface between CdS and Sb<sub>2</sub>S<sub>3</sub> is crucial for the overall performance. In this study, we conducted a highly effective sodium borohydride (NaBH<sub>4</sub>) etching to modify the CdS/Sb<sub>2</sub>S<sub>3</sub> interface, aiming to improve the device performance. The NaBH<sub>4</sub> etching led to a reduction in surface roughness and an enhancement in the hydrophilicity of the CdS layer, creating a more conducive environment for the subsequent deposition of the Sb<sub>2</sub>S<sub>3</sub> absorber layer. Simultaneously, the reduction of cadmium oxide serves to optimize interfacial energy alignment and minimize recombination losses. Ultimately, our full-inorganic Sb<sub>2</sub>S<sub>3</sub> solar cells, featuring the configuration FTO/CdS/Sb<sub>2</sub>S<sub>3</sub>/MnS/Carbon, attain a PCE of 6.26%. This marks a significant improvement of 15% compared to cells without NaBH<sub>4</sub> etching. This study presents a feasible and efficient perspective for modifying the CdS/Sb<sub>2</sub>S<sub>3</sub> interface, thereby enhancing the performance of Sb-based solar cells.</p></div>\",\"PeriodicalId\":429,\"journal\":{\"name\":\"Solar Energy Materials and Solar Cells\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-06-17\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy Materials and Solar Cells\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927024824003039\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024824003039","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Efficient CdS/Sb2S3 interfacial modification using sodium borohydride etching for enhanced performance of low-cost full-inorganic antimony-based solar cells
Antimony sulfide (Sb2S3) is a promising material for photovoltaic applications because of its high absorption coefficient, environmental friendliness and low cost. Nevertheless, the conversion efficiency of Sb2S3 solar cells severely deviates from theoretical predictions, and the interface between CdS and Sb2S3 is crucial for the overall performance. In this study, we conducted a highly effective sodium borohydride (NaBH4) etching to modify the CdS/Sb2S3 interface, aiming to improve the device performance. The NaBH4 etching led to a reduction in surface roughness and an enhancement in the hydrophilicity of the CdS layer, creating a more conducive environment for the subsequent deposition of the Sb2S3 absorber layer. Simultaneously, the reduction of cadmium oxide serves to optimize interfacial energy alignment and minimize recombination losses. Ultimately, our full-inorganic Sb2S3 solar cells, featuring the configuration FTO/CdS/Sb2S3/MnS/Carbon, attain a PCE of 6.26%. This marks a significant improvement of 15% compared to cells without NaBH4 etching. This study presents a feasible and efficient perspective for modifying the CdS/Sb2S3 interface, thereby enhancing the performance of Sb-based solar cells.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.