{"title":"从毫米到微米电极间距离的影响:是否有办法在废水处理过程中最大限度地提高有机污染物降解率,同时最大限度地减少阴极结垢和氯酸盐的形成?","authors":"Saad Diris , Faidzul Hakim Adnan , Marie-Noëlle Pons , Emmanuel Mousset","doi":"10.1016/j.electacta.2024.144596","DOIUrl":null,"url":null,"abstract":"<div><p>The influence of a range of inter-electrode distances from 50 µm to 1 mm has been investigated for the first time, in order to assess to possibility to maximize the degradation and mineralization efficiency, while minimizing the cathode scaling and the inorganic by-products formation. Tylosin has been selected as representative pharmaceutical pollutant in wastewater, while the influence of Ca<sup>2+</sup>, HCO<sub>3</sub><sup>−</sup>/CO<sub>3</sub><sup>2−</sup> and Cl<sup>−</sup> was carried out. Advanced electro-oxidation with boron-doped diamond (BDD) anode and stainless-steel cathode was implemented to treat this synthetic effluent in a scalable filter-press reactor operated in a recirculated batch flow-by mode.</p><p>The first interesting feature is that cathodic OH<sup>−</sup> and anodic H<sup>+</sup> formations were not counterbalanced at short micro-distances (50 µm), meaning that electro-precipitation (until 50 % of CaCO<sub>3</sub> precipitation) and degradation/mineralization (until 100 %) could still occur at such range of distance. Secondly, the gain of mass transfer at the shorter distance (50 µm) couldn't counteract the higher energy needed to achieve similar degradation efficiency compared to the distances of 500 µm and 1 mm. Lastly, too high distances such as 1 mm suffer from lower mass transfer compared to sub-millimetric distances. Thus, an intermediate distance of 500 µm led to better performance in terms of tylosin degradation (100 % of degradation, 39 % of mineralization), while minimizing electro-precipitation (26 % of CaCO<sub>3</sub> cathodic precipitation) and unwanted inorganic chlorinated by-products formation (ClO<sub>3</sub><sup>−</sup> = 2.8 mg L<sup>−1</sup>). This was obtained at a current density of 0.1 mA cm<sup>−2</sup>, leading to lower energy requirement (0.018 kWh g-tylosin<sup>−1</sup>). In these low-current conditions the formation of perchlorate could be avoided.</p></div>","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":null,"pages":null},"PeriodicalIF":5.5000,"publicationDate":"2024-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Impact of millimetric to micrometric inter-electrode distances: Is there a way to maximize the organic pollutant degradation yield and minimize the cathode scaling and chlorate formation during wastewater treatment?\",\"authors\":\"Saad Diris , Faidzul Hakim Adnan , Marie-Noëlle Pons , Emmanuel Mousset\",\"doi\":\"10.1016/j.electacta.2024.144596\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The influence of a range of inter-electrode distances from 50 µm to 1 mm has been investigated for the first time, in order to assess to possibility to maximize the degradation and mineralization efficiency, while minimizing the cathode scaling and the inorganic by-products formation. Tylosin has been selected as representative pharmaceutical pollutant in wastewater, while the influence of Ca<sup>2+</sup>, HCO<sub>3</sub><sup>−</sup>/CO<sub>3</sub><sup>2−</sup> and Cl<sup>−</sup> was carried out. Advanced electro-oxidation with boron-doped diamond (BDD) anode and stainless-steel cathode was implemented to treat this synthetic effluent in a scalable filter-press reactor operated in a recirculated batch flow-by mode.</p><p>The first interesting feature is that cathodic OH<sup>−</sup> and anodic H<sup>+</sup> formations were not counterbalanced at short micro-distances (50 µm), meaning that electro-precipitation (until 50 % of CaCO<sub>3</sub> precipitation) and degradation/mineralization (until 100 %) could still occur at such range of distance. Secondly, the gain of mass transfer at the shorter distance (50 µm) couldn't counteract the higher energy needed to achieve similar degradation efficiency compared to the distances of 500 µm and 1 mm. Lastly, too high distances such as 1 mm suffer from lower mass transfer compared to sub-millimetric distances. Thus, an intermediate distance of 500 µm led to better performance in terms of tylosin degradation (100 % of degradation, 39 % of mineralization), while minimizing electro-precipitation (26 % of CaCO<sub>3</sub> cathodic precipitation) and unwanted inorganic chlorinated by-products formation (ClO<sub>3</sub><sup>−</sup> = 2.8 mg L<sup>−1</sup>). This was obtained at a current density of 0.1 mA cm<sup>−2</sup>, leading to lower energy requirement (0.018 kWh g-tylosin<sup>−1</sup>). In these low-current conditions the formation of perchlorate could be avoided.</p></div>\",\"PeriodicalId\":305,\"journal\":{\"name\":\"Electrochimica Acta\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2024-06-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Electrochimica Acta\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0013468624008363\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013468624008363","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Impact of millimetric to micrometric inter-electrode distances: Is there a way to maximize the organic pollutant degradation yield and minimize the cathode scaling and chlorate formation during wastewater treatment?
The influence of a range of inter-electrode distances from 50 µm to 1 mm has been investigated for the first time, in order to assess to possibility to maximize the degradation and mineralization efficiency, while minimizing the cathode scaling and the inorganic by-products formation. Tylosin has been selected as representative pharmaceutical pollutant in wastewater, while the influence of Ca2+, HCO3−/CO32− and Cl− was carried out. Advanced electro-oxidation with boron-doped diamond (BDD) anode and stainless-steel cathode was implemented to treat this synthetic effluent in a scalable filter-press reactor operated in a recirculated batch flow-by mode.
The first interesting feature is that cathodic OH− and anodic H+ formations were not counterbalanced at short micro-distances (50 µm), meaning that electro-precipitation (until 50 % of CaCO3 precipitation) and degradation/mineralization (until 100 %) could still occur at such range of distance. Secondly, the gain of mass transfer at the shorter distance (50 µm) couldn't counteract the higher energy needed to achieve similar degradation efficiency compared to the distances of 500 µm and 1 mm. Lastly, too high distances such as 1 mm suffer from lower mass transfer compared to sub-millimetric distances. Thus, an intermediate distance of 500 µm led to better performance in terms of tylosin degradation (100 % of degradation, 39 % of mineralization), while minimizing electro-precipitation (26 % of CaCO3 cathodic precipitation) and unwanted inorganic chlorinated by-products formation (ClO3− = 2.8 mg L−1). This was obtained at a current density of 0.1 mA cm−2, leading to lower energy requirement (0.018 kWh g-tylosin−1). In these low-current conditions the formation of perchlorate could be avoided.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.