Kaiming Wang , Xin Gong , Xinyu Ye , Jinxu Li , Yang Yang , Huacheng Zhu , Yuesheng Wang , Liping Yan , Yanping Zhou
{"title":"通过合理的双层设计在生物炭上实施介电基因工程,实现超宽带微波吸收","authors":"Kaiming Wang , Xin Gong , Xinyu Ye , Jinxu Li , Yang Yang , Huacheng Zhu , Yuesheng Wang , Liping Yan , Yanping Zhou","doi":"10.1016/j.carbon.2024.119326","DOIUrl":null,"url":null,"abstract":"<div><p>Biomass char is very promising in developing microwave absorbing materials with low minimum reflection loss (RL<sub>min</sub>) and ultrawide effective absorption bandwidth (EAB) owing to its low cost and natural availability of various pores, but however is facing a dilemma between the conduction loss and interface polarization loss where new heating technology is highly desirable. In this work, a microwave confined plasma/microwave hybrid heating technology is developed based on the unique interaction between porous carbon and microwave for simultaneous enhancement of conduction loss and interface polarization loss of cellulose char. Compared to the conventional heating product at the same temperature, the as-prepared microwave char showed almost doubled conductivity which is beneficial for conduction loss, higher content of <em>C</em>–O bond that has longer bond length and dielectric susceptibility than C<img>O bond, and more condensed carbon nanoparticles embedded in the carbon matrix which is responsible for increasing the heterointerface polarization loss. As such the tangent loss of MW900-40 % ranges from 0.69 to 0.97 while that of CH900-40 % only ranges from 0.34 to 0.64 in the frequency range of 2.0–18.0 GHz. Further, based on multilayer impedance gradient principle, a double-layer absorber is constructed with products of different MW900 loading, yielding a RL<sub>min</sub> of −59.0 dB at 15.9 GHz with an EAB of 10.0 GHz at 4.0 mm, whose working mechanism is comprehensively studied by simulations in terms of impedance matching and microwave dissipation distribution.</p></div>","PeriodicalId":262,"journal":{"name":"Carbon","volume":null,"pages":null},"PeriodicalIF":10.5000,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dielectric gene engineering on biochar for ultrawide-band microwave absorption with a rational double-layer design\",\"authors\":\"Kaiming Wang , Xin Gong , Xinyu Ye , Jinxu Li , Yang Yang , Huacheng Zhu , Yuesheng Wang , Liping Yan , Yanping Zhou\",\"doi\":\"10.1016/j.carbon.2024.119326\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Biomass char is very promising in developing microwave absorbing materials with low minimum reflection loss (RL<sub>min</sub>) and ultrawide effective absorption bandwidth (EAB) owing to its low cost and natural availability of various pores, but however is facing a dilemma between the conduction loss and interface polarization loss where new heating technology is highly desirable. In this work, a microwave confined plasma/microwave hybrid heating technology is developed based on the unique interaction between porous carbon and microwave for simultaneous enhancement of conduction loss and interface polarization loss of cellulose char. Compared to the conventional heating product at the same temperature, the as-prepared microwave char showed almost doubled conductivity which is beneficial for conduction loss, higher content of <em>C</em>–O bond that has longer bond length and dielectric susceptibility than C<img>O bond, and more condensed carbon nanoparticles embedded in the carbon matrix which is responsible for increasing the heterointerface polarization loss. As such the tangent loss of MW900-40 % ranges from 0.69 to 0.97 while that of CH900-40 % only ranges from 0.34 to 0.64 in the frequency range of 2.0–18.0 GHz. Further, based on multilayer impedance gradient principle, a double-layer absorber is constructed with products of different MW900 loading, yielding a RL<sub>min</sub> of −59.0 dB at 15.9 GHz with an EAB of 10.0 GHz at 4.0 mm, whose working mechanism is comprehensively studied by simulations in terms of impedance matching and microwave dissipation distribution.</p></div>\",\"PeriodicalId\":262,\"journal\":{\"name\":\"Carbon\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":10.5000,\"publicationDate\":\"2024-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0008622324005451\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0008622324005451","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Dielectric gene engineering on biochar for ultrawide-band microwave absorption with a rational double-layer design
Biomass char is very promising in developing microwave absorbing materials with low minimum reflection loss (RLmin) and ultrawide effective absorption bandwidth (EAB) owing to its low cost and natural availability of various pores, but however is facing a dilemma between the conduction loss and interface polarization loss where new heating technology is highly desirable. In this work, a microwave confined plasma/microwave hybrid heating technology is developed based on the unique interaction between porous carbon and microwave for simultaneous enhancement of conduction loss and interface polarization loss of cellulose char. Compared to the conventional heating product at the same temperature, the as-prepared microwave char showed almost doubled conductivity which is beneficial for conduction loss, higher content of C–O bond that has longer bond length and dielectric susceptibility than CO bond, and more condensed carbon nanoparticles embedded in the carbon matrix which is responsible for increasing the heterointerface polarization loss. As such the tangent loss of MW900-40 % ranges from 0.69 to 0.97 while that of CH900-40 % only ranges from 0.34 to 0.64 in the frequency range of 2.0–18.0 GHz. Further, based on multilayer impedance gradient principle, a double-layer absorber is constructed with products of different MW900 loading, yielding a RLmin of −59.0 dB at 15.9 GHz with an EAB of 10.0 GHz at 4.0 mm, whose working mechanism is comprehensively studied by simulations in terms of impedance matching and microwave dissipation distribution.
期刊介绍:
The journal Carbon is an international multidisciplinary forum for communicating scientific advances in the field of carbon materials. It reports new findings related to the formation, structure, properties, behaviors, and technological applications of carbons. Carbons are a broad class of ordered or disordered solid phases composed primarily of elemental carbon, including but not limited to carbon black, carbon fibers and filaments, carbon nanotubes, diamond and diamond-like carbon, fullerenes, glassy carbon, graphite, graphene, graphene-oxide, porous carbons, pyrolytic carbon, and other sp2 and non-sp2 hybridized carbon systems. Carbon is the companion title to the open access journal Carbon Trends. Relevant application areas for carbon materials include biology and medicine, catalysis, electronic, optoelectronic, spintronic, high-frequency, and photonic devices, energy storage and conversion systems, environmental applications and water treatment, smart materials and systems, and structural and thermal applications.