聚(苯乙烯-甲基丙烯酸缩水甘油酯)胶乳的硼吸附研究:改性剂的影响

IF 2.4 3区 化学 Q3 POLYMER SCIENCE
Cansel Tuncer, Meliha Işık
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引用次数: 0

摘要

采用乳液聚合法合成了聚苯乙烯-甲基丙烯酸缩水甘油酯(PSGMA)胶乳。用 N-甲基-d-葡糖胺(NMDG)、1,2-双(3-氨基丙基氨基)乙烷(BAPE)、N-(2-羟乙基)乙二胺(HEA)和 N,N'-二甲基乙二胺(NMEA)对 PSGMA 胶乳进行改性。元素分析结果显示,N 的含量在 2.1% 到 4.4% 之间,这表明改性是成功的。使用这些改性胶乳进行了硼吸附研究。研究采用姜黄素法,通过紫外-可见分光光度法进行。最有效的吸附过程是在 pH 值为 9、硼浓度为 10 ppm 和接触时间为 60 分钟的条件下进行的。结果发现,与其他改性胶乳相比,用 NMDG 改性的胶乳具有更高的吸附容量(0.195 mmol/g)。通过动态光散射光谱法和扫描电子显微镜(SEM)分析确定了颗粒大小。扫描电子显微镜分析发现,PSGMA 胶乳的颗粒直径约为 140 nm,颗粒几乎是单分散的。用 NMDG、BAPE、HEA 和 NMEA 剂对 PSGMA 胶乳进行改性并进行硼吸附后,观察到颗粒直径分别增加到约 170、270、220 和 260 nm。使用元素分析仪测定了结构的 N%。使用热重分析仪测定了结构的 B2O3%。热分析研究表明,有机成分在 700 °C 时已从结构中完全去除,但在硼吸附聚合物中发现了 4.8% 至 10.4% 的残留物(%B2O3)。硼的含量是通过电感耦合等离子体质谱仪测定的。结果表明,吸附硼的量在 0.42% 到 0.95% 之间变化,其中用 NMDG 改性的胶乳吸附硼的量最高,这是因为它的结构非常简单,而且 -OH 基团的位置也很重要。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Boron adsorption studies of poly(styrene-glycidyl methacrylate) latex: effect of modification agents

Boron adsorption studies of poly(styrene-glycidyl methacrylate) latex: effect of modification agents

Boron adsorption studies of poly(styrene-glycidyl methacrylate) latex: effect of modification agents

Poly(styrene-glycidyl methacrylate) (PSGMA) latex was synthesized by emulsion polymerization method. PSGMA latex was modified with N-methyl-d-glucamine (NMDG), 1,2-bis(3-aminopropylamino)ethane (BAPE), N-(2-hydroxyethyl)ethylenediamine (HEA), and N,N'-dimethylethylenediamine (NMEA). The presence of N amount varying between 2.1 and 4.4% in the results of elemental analysis showed that the modification was successful. Boron adsorption studies were carried out using these modified latexes. The study was carried out using the curcumin method by UV–vis spectrophotometry. For the most effective adsorption process, at pH value of 9, the boron concentration was 10 ppm and the contact time was 60 min. It was found that latex modified with NMDG had a higher adsorption capacity (0.195 mmol/g) than other modified latexes. Particle sizes were determined by dynamic light scattering spectrometry and scanning electron microscopy (SEM) analyses. The particle diameter of PSGMA latex was found to be approximately 140 nm in SEM analysis and the particles were almost monodisperse. After PSGMA latex was modified with NMDG, BAPE, HEA, and NMEA agents and boron adsorption was performed, it was observed that the particle diameters increased to approximately 170, 270, 220, and 260 nm, respectively. An elemental analyzer was used to determine the %N of the structures. The %B2O3 of the structures was determined with a thermogravimetric analyzer. While thermal analysis studies showed that organic components were completely removed from the structure at 700 °C, residues ranging from 4.8 to 10.4% (%B2O3) were found in boron adsorption polymers. The %B amounts were determined with an inductively coupled plasma mass spectroscopy device. It was observed that the amount of adsorbed boron varied between 0.42 and 0.95%, and the highest amount of %B belonged to latex modified with NMDG due to its very simple structure and the location of the –OH groups.

Graphical Abstract

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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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