利用超光谱成像技术侦测渔业领域的欺诈行为

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Paula Luri Esplandiú, Juan-Jesús Marín-Méndez, Miriam Alonso-Santamaría, Berta Remírez-Moreno, M. Sáiz-Abajo
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引用次数: 0

摘要

目前,越来越多的消费者关注食品的质量、安全和真实性。渔业是第二大欺诈风险最高、认证问题最多的食品类别。有一些非破坏性、快速和准确的技术可用于实时认证,其中以高光谱成像(HSI)技术最为突出。在这种情况下,本研究的主要目的是探索在可见光和近红外(VIS-NIR)以及近红外(NIR)范围内使用高光谱成像技术检测凤尾鱼产地欺诈和未申报先前冷冻过程欺诈的可行性。所使用的光谱预处理方法包括标准正态变分法、萨维茨基-戈莱一阶衍生法和萨维茨基-戈莱二阶衍生法,并始终采用均值居中法(MC)。此外,还评估了在预处理前使用前一步平滑法的影响。建立分类模型时使用了两种分类算法:类比软独立建模和偏最小二乘判别分析(PLS-DA)。经过分析发现,使用 VIS-NIR 区域的建模结果总是优于使用 NIR 区域的建模结果,而 PLS-DA 方法的模型性能最好,新鲜鳀鱼的召回率为 0.97,冷冻解冻鳀鱼的召回率为 0.98,坎塔布里亚鳀鱼的召回率为 0.98,地中海鳀鱼的召回率为 0.96。该模型的一个优点是无需制备样品就能对测量鱼皮一侧的凤尾鱼进行分类。总之,研究结果表明,HSI 结合 PLS-DA 是快速、非破坏性识别鳀鱼新鲜度和产地掺假的有效方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Fraud detection in the fishing sector using hyperspectral imaging
Currently, more and more consumers are interested in the quality, safety, and authenticity of food products. The fishing sector is the second food category with the highest risk of fraud and the greatest presence of authentication problems. There are non-destructive, fast and accurate techniques for real-time authentication, with hyperspectral imaging (HSI) standing out among these. In this context, the main aim of this study is to explore the viability of HSI in the visible and near infrared (VIS-NIR) and near infrared (NIR) ranges for the detection of fraud by origin and by non-declaration of the previous freezing process, in anchovies. The spectral pretreatment methods used were the standard normal variate method, the Savitzky-Golay 1st derivate and the Savitzky-Golay 2nd derivate, always followed by mean centering (MC). In addition, the impact of using a previous step of smoothing prior to pretreatment was also evaluated. Two classification algorithms: soft independent modeling of class analogy, and partial least squares discriminant analysis (PLS-DA) were used to build the classification model. After analysis, it was found that the modelling results using the VIS-NIR region were always better than those using the NIR region, and the best performing model was by PLS-DA with a recall of 0.97 for fresh and 0.98 for frozen-thawed anchovies and 0.98 for Cantabrian anchovies and 0.96 for Mediterranean anchovies. One advantage of the model obtained is the ability to classify the anchovies measuring on the skin side of fish without the need for sample preparation. Overall, the results showed that HSI combined with PLS-DA is a favorable solution for rapid, and non-destructive recognition of adulteration regarding freshness and origin in anchovies.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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