木质微光落在非反应基质上的发光燃烧计算研究

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Jiuling Yang, Xiaofeng Peng, James Urban, Wei Huang, Haoliang Wang, Shaojia Wang, Yuqi Hu
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引用次数: 0

摘要

尽管野火中由余烬点燃的频率越来越高,但对余烬燃烧内在的多种物理化学过程的研究却很有限。本研究提出了一个二维计算模型来研究木质微火的燃烧过程。该模型采用全局炭氧化反应来表示木质微粒的燃烧过程。参数研究表明,孔隙率、反应热和氧气浓度是对木质微光燃烧影响最大的参数。然后,将该模型与一系列台架规模实验进行了比较,比较了暴露在热微光下的发光时间和未发生反应的基质的热反应。模拟结果表明,微光燃烧主要由扩散控制而非动力学控制。因此,鉴于点火中微粒的多样性,建模者应更多地关注微粒种类之间的物理性质差异,而不是动力学差异。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Computational study on the glowing combustion of a wooden ember landing on a non-reacting substrate
Despite the increasing frequency in spot ignition by embers in wildfires, research on the multiple physicochemical processes intrinsic to ember combustion is limited. In this study, a two-dimensional computational model was proposed to study the glowing combustion of a wooden ember. A global char oxidation reaction was used to represent the glowing combustion of the ember. A parametric study showed that the porosity, heat of reaction, and oxygen concentration were the most influential parameters on the ember combustion. Then, the model was compared to a series of bench-scale experiments in terms of glowing time and thermal response of a non-reacting substrate when exposed to a hot ember. The simulation results showed that ember combustion was mostly diffusion-controlled rather than kinetic-controlled. Thus, given the ember diversities in spotting fire, modelers should pay more attention to the difference in the physical properties instead of the kinetics between ember species.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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