Elif Özcan, Derya Davarcı, H. Cengiz Yatmaz and Yunus Zorlu*,
{"title":"通过环三膦烯功能化构造和特吡啶-钳配体设计配位框架,实现有机染料的高效光催化降解","authors":"Elif Özcan, Derya Davarcı, H. Cengiz Yatmaz and Yunus Zorlu*, ","doi":"10.1021/acs.cgd.4c00237","DOIUrl":null,"url":null,"abstract":"<p >Engineering the Cd(II) coordination sphere with a terpyridine-pincer ligand and tuning the cyclotriphosphazene-fuctionalized multicarboxylates (<b>H</b><sub><b>4</b></sub><b>L1, H</b><sub><b>4</b></sub><b>L2</b>) produced one-dimensionally oriented self-assemblies, namely, [{Cd<sub>2</sub>(trp)<sub>2</sub>(L1)}]·DMF·3H<sub>2</sub>O (<b>PCP-1</b>) and [{Cd<sub>2</sub>(trp)<sub>2</sub>(L2)}]·2DMF·H<sub>2</sub>O (<b>PCP-2</b>). The solid-state structures of <b>PCP-1</b> and <b>PCP-2</b> were characterized by Fourier-transform infrared spectroscopy (FTIR), single-crystal and powder X-ray diffractions (SC and PXRD), thermal analyses (TGA), scanning electron microscopy-energy dispersive X-ray (SEM-EDX) analysis, and ultraviolet–visible diffuse reflectance measurements (UV-DRS) analysis. Both coordination polymers demonstrated efficient photocatalytic performance in the degradation of four organic dyes, namely, methylene blue (MB), methyl orange (MO), rhodamine B (RhB), and reactive orange 16 (RO16) under UVA light irradiation. Terpyridine aromatic rings exhibit strong π–π interactions (d(π···π) < 3.8 Å) that influence the formation of three-dimensional (3D) supramolecular network of <b>PCP-1</b> and <b>PCP-2</b> and thus can improve photocatalytic efficiency. Additionally, a plausible photocatalytic mechanism has been proposed through trapping experiments of active species to enhance our understanding of the photocatalytic degradation of dyes. Notably, the photocatalytic degradation activities of <b>PCP-1</b> and <b>PCP-2</b> are remarkably efficient in the degradation of MB with a rate of 96 and 91%, respectively, at 20 ppm dye concentration and 300 mg/L photocatalyst concentration. Also, <b>PCP-1</b> and <b>PCP-2</b> displayed high emission in the solid state. These findings contribute to understanding the potential of the cyclophosphazene-based coordination polymers in environmental remediation.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":null,"pages":null},"PeriodicalIF":3.2000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Engineering Coordination Frameworks by Cyclotriphosphazene-Functionalized Tectonics and a Terpyridine-Pincer Ligand for Efficient Photocatalytic Degradation of Organic Dyes\",\"authors\":\"Elif Özcan, Derya Davarcı, H. Cengiz Yatmaz and Yunus Zorlu*, \",\"doi\":\"10.1021/acs.cgd.4c00237\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Engineering the Cd(II) coordination sphere with a terpyridine-pincer ligand and tuning the cyclotriphosphazene-fuctionalized multicarboxylates (<b>H</b><sub><b>4</b></sub><b>L1, H</b><sub><b>4</b></sub><b>L2</b>) produced one-dimensionally oriented self-assemblies, namely, [{Cd<sub>2</sub>(trp)<sub>2</sub>(L1)}]·DMF·3H<sub>2</sub>O (<b>PCP-1</b>) and [{Cd<sub>2</sub>(trp)<sub>2</sub>(L2)}]·2DMF·H<sub>2</sub>O (<b>PCP-2</b>). The solid-state structures of <b>PCP-1</b> and <b>PCP-2</b> were characterized by Fourier-transform infrared spectroscopy (FTIR), single-crystal and powder X-ray diffractions (SC and PXRD), thermal analyses (TGA), scanning electron microscopy-energy dispersive X-ray (SEM-EDX) analysis, and ultraviolet–visible diffuse reflectance measurements (UV-DRS) analysis. Both coordination polymers demonstrated efficient photocatalytic performance in the degradation of four organic dyes, namely, methylene blue (MB), methyl orange (MO), rhodamine B (RhB), and reactive orange 16 (RO16) under UVA light irradiation. Terpyridine aromatic rings exhibit strong π–π interactions (d(π···π) < 3.8 Å) that influence the formation of three-dimensional (3D) supramolecular network of <b>PCP-1</b> and <b>PCP-2</b> and thus can improve photocatalytic efficiency. Additionally, a plausible photocatalytic mechanism has been proposed through trapping experiments of active species to enhance our understanding of the photocatalytic degradation of dyes. Notably, the photocatalytic degradation activities of <b>PCP-1</b> and <b>PCP-2</b> are remarkably efficient in the degradation of MB with a rate of 96 and 91%, respectively, at 20 ppm dye concentration and 300 mg/L photocatalyst concentration. Also, <b>PCP-1</b> and <b>PCP-2</b> displayed high emission in the solid state. 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Engineering Coordination Frameworks by Cyclotriphosphazene-Functionalized Tectonics and a Terpyridine-Pincer Ligand for Efficient Photocatalytic Degradation of Organic Dyes
Engineering the Cd(II) coordination sphere with a terpyridine-pincer ligand and tuning the cyclotriphosphazene-fuctionalized multicarboxylates (H4L1, H4L2) produced one-dimensionally oriented self-assemblies, namely, [{Cd2(trp)2(L1)}]·DMF·3H2O (PCP-1) and [{Cd2(trp)2(L2)}]·2DMF·H2O (PCP-2). The solid-state structures of PCP-1 and PCP-2 were characterized by Fourier-transform infrared spectroscopy (FTIR), single-crystal and powder X-ray diffractions (SC and PXRD), thermal analyses (TGA), scanning electron microscopy-energy dispersive X-ray (SEM-EDX) analysis, and ultraviolet–visible diffuse reflectance measurements (UV-DRS) analysis. Both coordination polymers demonstrated efficient photocatalytic performance in the degradation of four organic dyes, namely, methylene blue (MB), methyl orange (MO), rhodamine B (RhB), and reactive orange 16 (RO16) under UVA light irradiation. Terpyridine aromatic rings exhibit strong π–π interactions (d(π···π) < 3.8 Å) that influence the formation of three-dimensional (3D) supramolecular network of PCP-1 and PCP-2 and thus can improve photocatalytic efficiency. Additionally, a plausible photocatalytic mechanism has been proposed through trapping experiments of active species to enhance our understanding of the photocatalytic degradation of dyes. Notably, the photocatalytic degradation activities of PCP-1 and PCP-2 are remarkably efficient in the degradation of MB with a rate of 96 and 91%, respectively, at 20 ppm dye concentration and 300 mg/L photocatalyst concentration. Also, PCP-1 and PCP-2 displayed high emission in the solid state. These findings contribute to understanding the potential of the cyclophosphazene-based coordination polymers in environmental remediation.
期刊介绍:
The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials.
Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.