Mingmin Zhu , Jing Wang , Yanxiao Zhang , Jie Wang , Qing Xu , Ming Liu
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引用次数: 0
摘要
为了揭示氟离子(F-)对 CoCrMo 牙科修复体被动膜耐腐蚀性和成分的影响。采用电化学和表面技术对铸造 Vitallium 2000 CoCrMo 系列合金的钝性进行了系统研究。结果表明,F- 对铸造 CoCrMo 在口腔环境中的被动膜耐腐蚀性有一定影响,F- 浓度的增加会减弱被动膜耐腐蚀性。随着 F- 浓度的增加,开路电位负向移动,腐蚀电流密度增大,极化电阻减小,被动膜缺陷密度增大。随着浸泡时间的延长,合金的耐腐蚀性会增强,并表现出以下特点AS > AS + 0.5 wt% NaF > AS + 1 wt% NaF。F- 的加入可使 Co、Cr 和 Mo 的峰值急剧下降,并促进被动膜的溶解。本研究结果可调节和指导口服含氟产品的应用剂量。
Corrosion characteristic of vitallium 2000 CoCrMo casting alloy in fluoride containing artificial saliva
In order to reveal the effect of fluoride ions (F−) on the passive film corrosion resistance and composition of CoCrMo dental prosthesis. The passivity of casting Vitallium 2000 CoCrMo series alloy was systematically studied by adopting electrochemical and surface techniques. The results show that F− have a certain effect on the passive film corrosion resistance of casting CoCrMo in oral environment, and the increase of F− concentration weakens the passive film corrosion resistance. With the increase of F− concentration, the open circuit potential moves negatively, the corrosion current density increases, the polarization resistance decreases, and the defect density in the passive film increases. With the extension of immersion time, the corrosion resistance of alloy will be enhanced and shows: AS > AS + 0.5 wt% NaF > AS + 1 wt% NaF. The addition of F− can decrease Co, Cr and Mo peaks sharply and promote the dissolution of the passive film. The result of present study could regulate and guide the application dose of oral fluorine-containing products.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.