Trinh Hao Nguyen , Nhat Minh Nguyen , Thien Phuoc Nguyen , Dao Anh Le Nguyen , Ha Bich Phan , Mai Ngoc Thi Le , Khoa Dang Nguyen , Phuong Hoang Tran
{"title":"在连续流动条件下将葡萄糖转化为 5-羟甲基糠醛的高效方法","authors":"Trinh Hao Nguyen , Nhat Minh Nguyen , Thien Phuoc Nguyen , Dao Anh Le Nguyen , Ha Bich Phan , Mai Ngoc Thi Le , Khoa Dang Nguyen , Phuong Hoang Tran","doi":"10.1016/j.jil.2024.100101","DOIUrl":null,"url":null,"abstract":"<div><p>5-Hydroxymethylfurfural (HMF) has emerged as a promising link between biomass and petrochemical products, offering great potential for application and promising market prospects. In this work, we investigated the catalyst for the synthesis of 5-hydroxymethylfurfural (HMF) from glucose using metal chloride or ionic liquid bearing Brönsted and Lewis acid using the continuous flow method. Under optimal conditions, a high HMF yield of 58 % was achieved at 120 °C within 20 min using IL 2/DMSO. For the study on metal chlorides, the reaction yield reached about 43 % HMF within 60 min using AlCl<sub>3</sub> (1 mmol) anhydrous. This research presents a remarkably effective method for synthesizing HMF.</p></div>","PeriodicalId":100794,"journal":{"name":"Journal of Ionic Liquids","volume":"4 2","pages":"Article 100101"},"PeriodicalIF":0.0000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772422024000247/pdfft?md5=a1d7e20adaf18ca8ad86392926901104&pid=1-s2.0-S2772422024000247-main.pdf","citationCount":"0","resultStr":"{\"title\":\"An efficient approach for the conversion of glucose into 5-hydroxymethylfurfural under continuous-flow condition\",\"authors\":\"Trinh Hao Nguyen , Nhat Minh Nguyen , Thien Phuoc Nguyen , Dao Anh Le Nguyen , Ha Bich Phan , Mai Ngoc Thi Le , Khoa Dang Nguyen , Phuong Hoang Tran\",\"doi\":\"10.1016/j.jil.2024.100101\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>5-Hydroxymethylfurfural (HMF) has emerged as a promising link between biomass and petrochemical products, offering great potential for application and promising market prospects. In this work, we investigated the catalyst for the synthesis of 5-hydroxymethylfurfural (HMF) from glucose using metal chloride or ionic liquid bearing Brönsted and Lewis acid using the continuous flow method. Under optimal conditions, a high HMF yield of 58 % was achieved at 120 °C within 20 min using IL 2/DMSO. For the study on metal chlorides, the reaction yield reached about 43 % HMF within 60 min using AlCl<sub>3</sub> (1 mmol) anhydrous. This research presents a remarkably effective method for synthesizing HMF.</p></div>\",\"PeriodicalId\":100794,\"journal\":{\"name\":\"Journal of Ionic Liquids\",\"volume\":\"4 2\",\"pages\":\"Article 100101\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2772422024000247/pdfft?md5=a1d7e20adaf18ca8ad86392926901104&pid=1-s2.0-S2772422024000247-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Ionic Liquids\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2772422024000247\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Ionic Liquids","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2772422024000247","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
An efficient approach for the conversion of glucose into 5-hydroxymethylfurfural under continuous-flow condition
5-Hydroxymethylfurfural (HMF) has emerged as a promising link between biomass and petrochemical products, offering great potential for application and promising market prospects. In this work, we investigated the catalyst for the synthesis of 5-hydroxymethylfurfural (HMF) from glucose using metal chloride or ionic liquid bearing Brönsted and Lewis acid using the continuous flow method. Under optimal conditions, a high HMF yield of 58 % was achieved at 120 °C within 20 min using IL 2/DMSO. For the study on metal chlorides, the reaction yield reached about 43 % HMF within 60 min using AlCl3 (1 mmol) anhydrous. This research presents a remarkably effective method for synthesizing HMF.
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