{"title":"LED 照明下二维 Ruddlesden-Popper 包晶太阳能电池的设计与模拟:ETL 和前接触带排列的作用","authors":"Tarek I. Alanazi , Ahmed Shaker , Walid Zein","doi":"10.1016/j.solmat.2024.112992","DOIUrl":null,"url":null,"abstract":"<div><p>This paper focuses on the design and simulation of 2D Ruddlesden-Popper halide perovskite (RPHP) solar cells, emphasizing their optimization for indoor LED illumination conditions. The design process begins with the validation of physical models within the SCAPS device simulator, accomplished through careful calibration against experimental (MAMP)MA<sub>n−1</sub>Pb<sub>n</sub>I<sub>3n+1</sub> RPHP cell data. Subsequently, different values of <n> (with n = 1, 2, 3, and 4) are explored to study the impact of different band gap energies, aiming to identify the most suitable option for optimal efficiency across diverse LED color temperatures. By addressing both material-specific considerations and device architecture optimization, this study aims to establish a comprehensive framework for designing RPHP solar cells tailored for white LED illumination. Additionally, the simulation reveals that optimizing the electron affinity of the Electron Transport Layer (ETL) significantly impacts device performance, with efficiencies exceeding 25 %. Furthermore, the study discusses emerging trends such as ETL-free structures, which aim to address interface defects and enhance device performance. In addition, we analyze the impact of bulk trap density and thickness of the 2-D perovskite absorber on efficiency limitations. With an absorber thickness set at 800 nm, a marginal decrease in PCE is observed, for the ETL-free solar cell, from around 34 % to 32 % as the trap density ranges from 10<sup>11</sup> to 10<sup>14</sup> cm<sup>−3</sup>. In contrast, for the ETL-based structure with the same variations, PCE experiences a substantial decline, dropping from approximately 47 % to 37 %. While the ETL-free structure may exhibit a lower PCE compared to the ETL-based cell, its capacity to endure fluctuations in trap density offers a notable advantage.</p><p>These efforts underscore the potential of 2D RPHP photovoltaic cells for indoor applications, presenting a pathway towards efficient, stable, and cost-effective photovoltaic technology suited for diverse lighting environments.</p></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":null,"pages":null},"PeriodicalIF":6.3000,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Design and simulation of 2D Ruddlesden–Popper perovskite solar cells under LED illumination: Role of ETL and front contact band alignment\",\"authors\":\"Tarek I. Alanazi , Ahmed Shaker , Walid Zein\",\"doi\":\"10.1016/j.solmat.2024.112992\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This paper focuses on the design and simulation of 2D Ruddlesden-Popper halide perovskite (RPHP) solar cells, emphasizing their optimization for indoor LED illumination conditions. The design process begins with the validation of physical models within the SCAPS device simulator, accomplished through careful calibration against experimental (MAMP)MA<sub>n−1</sub>Pb<sub>n</sub>I<sub>3n+1</sub> RPHP cell data. Subsequently, different values of <n> (with n = 1, 2, 3, and 4) are explored to study the impact of different band gap energies, aiming to identify the most suitable option for optimal efficiency across diverse LED color temperatures. By addressing both material-specific considerations and device architecture optimization, this study aims to establish a comprehensive framework for designing RPHP solar cells tailored for white LED illumination. Additionally, the simulation reveals that optimizing the electron affinity of the Electron Transport Layer (ETL) significantly impacts device performance, with efficiencies exceeding 25 %. Furthermore, the study discusses emerging trends such as ETL-free structures, which aim to address interface defects and enhance device performance. In addition, we analyze the impact of bulk trap density and thickness of the 2-D perovskite absorber on efficiency limitations. With an absorber thickness set at 800 nm, a marginal decrease in PCE is observed, for the ETL-free solar cell, from around 34 % to 32 % as the trap density ranges from 10<sup>11</sup> to 10<sup>14</sup> cm<sup>−3</sup>. In contrast, for the ETL-based structure with the same variations, PCE experiences a substantial decline, dropping from approximately 47 % to 37 %. While the ETL-free structure may exhibit a lower PCE compared to the ETL-based cell, its capacity to endure fluctuations in trap density offers a notable advantage.</p><p>These efforts underscore the potential of 2D RPHP photovoltaic cells for indoor applications, presenting a pathway towards efficient, stable, and cost-effective photovoltaic technology suited for diverse lighting environments.</p></div>\",\"PeriodicalId\":429,\"journal\":{\"name\":\"Solar Energy Materials and Solar Cells\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy Materials and Solar Cells\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927024824003040\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024824003040","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Design and simulation of 2D Ruddlesden–Popper perovskite solar cells under LED illumination: Role of ETL and front contact band alignment
This paper focuses on the design and simulation of 2D Ruddlesden-Popper halide perovskite (RPHP) solar cells, emphasizing their optimization for indoor LED illumination conditions. The design process begins with the validation of physical models within the SCAPS device simulator, accomplished through careful calibration against experimental (MAMP)MAn−1PbnI3n+1 RPHP cell data. Subsequently, different values of <n> (with n = 1, 2, 3, and 4) are explored to study the impact of different band gap energies, aiming to identify the most suitable option for optimal efficiency across diverse LED color temperatures. By addressing both material-specific considerations and device architecture optimization, this study aims to establish a comprehensive framework for designing RPHP solar cells tailored for white LED illumination. Additionally, the simulation reveals that optimizing the electron affinity of the Electron Transport Layer (ETL) significantly impacts device performance, with efficiencies exceeding 25 %. Furthermore, the study discusses emerging trends such as ETL-free structures, which aim to address interface defects and enhance device performance. In addition, we analyze the impact of bulk trap density and thickness of the 2-D perovskite absorber on efficiency limitations. With an absorber thickness set at 800 nm, a marginal decrease in PCE is observed, for the ETL-free solar cell, from around 34 % to 32 % as the trap density ranges from 1011 to 1014 cm−3. In contrast, for the ETL-based structure with the same variations, PCE experiences a substantial decline, dropping from approximately 47 % to 37 %. While the ETL-free structure may exhibit a lower PCE compared to the ETL-based cell, its capacity to endure fluctuations in trap density offers a notable advantage.
These efforts underscore the potential of 2D RPHP photovoltaic cells for indoor applications, presenting a pathway towards efficient, stable, and cost-effective photovoltaic technology suited for diverse lighting environments.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.