{"title":"氯化物共晶盐高温相变大胶囊的制备和蓄热特性","authors":"Lijuan Zhang , Hongwei Zhu , Lingxiao Zeng , Nan Sheng , Zhonghao Rao , Chunyu Zhu","doi":"10.1016/j.solmat.2024.112972","DOIUrl":null,"url":null,"abstract":"<div><p>Chloride salts, as high-temperature phase change materials (PCMs), have advantages in terms of high application temperature and high latent heat, but the intrinsic disadvantages such as high corrosiveness and easy leakage have seriously limited their development. Employing the NaCl–KCl binary salt as PCM, a double-shell cladding strategy with an inner layer of expanded graphite and an outer layer of ceramic was proposed, thereby, the chloride phase change macrocapsule with good thermal storage performance was successfully prepared. The double-shell capsules exhibited better leakage resistance and cycling stability. On this basis, the preparation process of double-shell eutectic salt macrocapsules was simplified by using an in-situ melting method, employing the mixed NaCl and KCl as raw materials directly that were transferred to eutectic binary salt inside the capsules during sintering. It is also proposed to improve the heat storage density of the capsules by increasing the capsule size and isostatically pressing the capsule. The NaK-20-200MPa sample indicated the largest heat storage density in the temperature range from 600 °C to 700 °C, with a mass heat storage density of 190.38 J/g, which was 2.85 % higher than that of the NaK-20-0MPa capsules and 36.99 % higher than that of the NaK-5-0MPa capsules. Additionally, the volume heat storage density of the NaK-20-200MPa capsules was 339.19 J/cm<sup>3</sup>, which was 14.69 % higher than that of the NaK-20-0MPa capsules and 21.52 % higher than that of the NaK-5-0MPa capsules. The good thermal performance and low cost of chloride PCM could ensure the encapsulated salt for use in high-temperature heat storage.</p></div>","PeriodicalId":429,"journal":{"name":"Solar Energy Materials and Solar Cells","volume":null,"pages":null},"PeriodicalIF":6.3000,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation and heat storage characteristics of high-temperature phase change macrocapsules of chloride eutectic salt\",\"authors\":\"Lijuan Zhang , Hongwei Zhu , Lingxiao Zeng , Nan Sheng , Zhonghao Rao , Chunyu Zhu\",\"doi\":\"10.1016/j.solmat.2024.112972\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Chloride salts, as high-temperature phase change materials (PCMs), have advantages in terms of high application temperature and high latent heat, but the intrinsic disadvantages such as high corrosiveness and easy leakage have seriously limited their development. Employing the NaCl–KCl binary salt as PCM, a double-shell cladding strategy with an inner layer of expanded graphite and an outer layer of ceramic was proposed, thereby, the chloride phase change macrocapsule with good thermal storage performance was successfully prepared. The double-shell capsules exhibited better leakage resistance and cycling stability. On this basis, the preparation process of double-shell eutectic salt macrocapsules was simplified by using an in-situ melting method, employing the mixed NaCl and KCl as raw materials directly that were transferred to eutectic binary salt inside the capsules during sintering. It is also proposed to improve the heat storage density of the capsules by increasing the capsule size and isostatically pressing the capsule. The NaK-20-200MPa sample indicated the largest heat storage density in the temperature range from 600 °C to 700 °C, with a mass heat storage density of 190.38 J/g, which was 2.85 % higher than that of the NaK-20-0MPa capsules and 36.99 % higher than that of the NaK-5-0MPa capsules. Additionally, the volume heat storage density of the NaK-20-200MPa capsules was 339.19 J/cm<sup>3</sup>, which was 14.69 % higher than that of the NaK-20-0MPa capsules and 21.52 % higher than that of the NaK-5-0MPa capsules. The good thermal performance and low cost of chloride PCM could ensure the encapsulated salt for use in high-temperature heat storage.</p></div>\",\"PeriodicalId\":429,\"journal\":{\"name\":\"Solar Energy Materials and Solar Cells\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solar Energy Materials and Solar Cells\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0927024824002848\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solar Energy Materials and Solar Cells","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0927024824002848","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Preparation and heat storage characteristics of high-temperature phase change macrocapsules of chloride eutectic salt
Chloride salts, as high-temperature phase change materials (PCMs), have advantages in terms of high application temperature and high latent heat, but the intrinsic disadvantages such as high corrosiveness and easy leakage have seriously limited their development. Employing the NaCl–KCl binary salt as PCM, a double-shell cladding strategy with an inner layer of expanded graphite and an outer layer of ceramic was proposed, thereby, the chloride phase change macrocapsule with good thermal storage performance was successfully prepared. The double-shell capsules exhibited better leakage resistance and cycling stability. On this basis, the preparation process of double-shell eutectic salt macrocapsules was simplified by using an in-situ melting method, employing the mixed NaCl and KCl as raw materials directly that were transferred to eutectic binary salt inside the capsules during sintering. It is also proposed to improve the heat storage density of the capsules by increasing the capsule size and isostatically pressing the capsule. The NaK-20-200MPa sample indicated the largest heat storage density in the temperature range from 600 °C to 700 °C, with a mass heat storage density of 190.38 J/g, which was 2.85 % higher than that of the NaK-20-0MPa capsules and 36.99 % higher than that of the NaK-5-0MPa capsules. Additionally, the volume heat storage density of the NaK-20-200MPa capsules was 339.19 J/cm3, which was 14.69 % higher than that of the NaK-20-0MPa capsules and 21.52 % higher than that of the NaK-5-0MPa capsules. The good thermal performance and low cost of chloride PCM could ensure the encapsulated salt for use in high-temperature heat storage.
期刊介绍:
Solar Energy Materials & Solar Cells is intended as a vehicle for the dissemination of research results on materials science and technology related to photovoltaic, photothermal and photoelectrochemical solar energy conversion. Materials science is taken in the broadest possible sense and encompasses physics, chemistry, optics, materials fabrication and analysis for all types of materials.