Aigialomycin D 的另一种全合成方法

IF 1.8 3区化学 Q3 CHEMISTRY, ORGANIC

Synthetic Communications Pub Date : 2024-05-29 DOI:10.1080/00397911.2024.2358355

Sudhakar D G S , Venkata Ramana Reddy Ch , Tasqeeruddin Syed , Gattu Sridhar , Srinivasa Rao Alapati

引用次数: 0

摘要

利用廉价且常见的起始原料，通过简单、高效和立体选择性的方法合成了 14 元苯并大内酯--Aigialomycin D。这种聚合合成的主要步骤是科里-富克斯反应、山口酯化和闭环偏析（RCM）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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An alternative total synthesis of Aigialomycin D

Aigialomycin D, a 14-membered benzannulated macrolactone, was synthesized in a simple, efficient and stereoselective approach using inexpensive and commonly accessible starting materials. The main steps in this convergent synthesis are Corey-Fuchs reaction, Yamaguchi esterification and ring closing metathesis (RCM).

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来源期刊

Synthetic Communications 化学-有机化学

CiteScore

4.40

自引率

4.80%

发文量

156

审稿时长

4.3 months

期刊介绍： Synthetic Communications presents communications describing new methods, reagents, and other synthetic work pertaining to organic chemistry with sufficient experimental detail to permit reported reactions to be repeated by a chemist reasonably skilled in the art. In addition, the Journal features short, focused review articles discussing topics within its remit of synthetic organic chemistry.