Shu Okamoto, Dr. Yoshifumi Hashikawa, Prof. Dr. Yasujiro Murata
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Front Cover: Phosphine-Mediated Dimerization of Open-[60]Fullerenes (Chem. Asian J. 11/2024)
The cover image shows a self-assembled structure of two open-[60]fullerene dimers. The synthesis of the dimer requires the use of phosphine which in situ produces ylide and α-methylene carbonyl variants of an open-[60]fullerene monomer. Nevertheless, control experiments excluded reaction mechanisms via Wittig reaction and aldol condensation. Alternatively, the computational study suggested a betaine variant of the monomer as a nucleophile to realize intermolecular C–C bond formation. In this transformation, homo- and heterochiral dimers would be potentially yielded while a rate-determining step was suggested to be different from each other. More details can be found in article number e202400142 by Shu Okamoto, Yoshifumi Hashikawa, and Yasujiro Murata.
期刊介绍:
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).