{"title":"热压烧结 Nb5Cr 超级合金的力学性能和氧化行为","authors":"Zhenjie Sun","doi":"10.1134/S1067821224600042","DOIUrl":null,"url":null,"abstract":"<p>In this paper, an alloy with a group of Nb5Cr was prepared by hot pressing sintering and its phase composition was characterized. After hot pressing sintering, Cr element exists in the form of solid solution outside the Nb matrix, and a certain amount of NbCr<sub>2</sub> phase is formed. The bending strength of the obtained alloys is not less than 250 MPa, and the fracture toughness is close to that of H11 casting die steel. In addition to the mechanical properties of the alloy, the oxidation behavior of the alloy at different temperatures was also studied. The experimental results show that the change of the alloy is not obvious at 1000°C except for the dissolution of Cr element, and at 1000–1200°C, the alloy can spontaneously form a CrNbO<sub>4</sub> oxide film which is weakly bound to the alloy matrix. This is very conducive to the application of separation between the mold and the casting mold during casting. This product provides the casting industry with a material that can spontaneously form a Self-oxidizing film under high temperature oxidation environment and provides a usable choice for materials used in high temperature casting environment.</p>","PeriodicalId":765,"journal":{"name":"Russian Journal of Non-Ferrous Metals","volume":null,"pages":null},"PeriodicalIF":0.6000,"publicationDate":"2024-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanical Properties and Oxidation Behavior of Hot Pressing Sintered Nb5Cr Superalloy\",\"authors\":\"Zhenjie Sun\",\"doi\":\"10.1134/S1067821224600042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this paper, an alloy with a group of Nb5Cr was prepared by hot pressing sintering and its phase composition was characterized. After hot pressing sintering, Cr element exists in the form of solid solution outside the Nb matrix, and a certain amount of NbCr<sub>2</sub> phase is formed. The bending strength of the obtained alloys is not less than 250 MPa, and the fracture toughness is close to that of H11 casting die steel. In addition to the mechanical properties of the alloy, the oxidation behavior of the alloy at different temperatures was also studied. The experimental results show that the change of the alloy is not obvious at 1000°C except for the dissolution of Cr element, and at 1000–1200°C, the alloy can spontaneously form a CrNbO<sub>4</sub> oxide film which is weakly bound to the alloy matrix. This is very conducive to the application of separation between the mold and the casting mold during casting. This product provides the casting industry with a material that can spontaneously form a Self-oxidizing film under high temperature oxidation environment and provides a usable choice for materials used in high temperature casting environment.</p>\",\"PeriodicalId\":765,\"journal\":{\"name\":\"Russian Journal of Non-Ferrous Metals\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-06-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Non-Ferrous Metals\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1067821224600042\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Non-Ferrous Metals","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1067821224600042","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Mechanical Properties and Oxidation Behavior of Hot Pressing Sintered Nb5Cr Superalloy
In this paper, an alloy with a group of Nb5Cr was prepared by hot pressing sintering and its phase composition was characterized. After hot pressing sintering, Cr element exists in the form of solid solution outside the Nb matrix, and a certain amount of NbCr2 phase is formed. The bending strength of the obtained alloys is not less than 250 MPa, and the fracture toughness is close to that of H11 casting die steel. In addition to the mechanical properties of the alloy, the oxidation behavior of the alloy at different temperatures was also studied. The experimental results show that the change of the alloy is not obvious at 1000°C except for the dissolution of Cr element, and at 1000–1200°C, the alloy can spontaneously form a CrNbO4 oxide film which is weakly bound to the alloy matrix. This is very conducive to the application of separation between the mold and the casting mold during casting. This product provides the casting industry with a material that can spontaneously form a Self-oxidizing film under high temperature oxidation environment and provides a usable choice for materials used in high temperature casting environment.
期刊介绍：
Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.
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