Xingxiang Fan, Na Wu, Lida Sun, Yan Jiang, Shasha He, Mengyang Huang, Kunbin Yang, Yang Cao
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New separation technology for lead and mercury from acid sludge of copper smelting using a total hydrometallurgical process
The separation of lead (Pb) and mercury (Hg) from copper (Cu) smelting acid sludge using the carbonization and acid-leaching total hydrometallurgical process was investigated. The effects of the excess coefficient of sodium carbonate, excess coefficient of nitric acid, conversion time, conversion temperature, dissolution time, and dissolution temperature on the separation efficiency of Pb and Hg were studied. The test results indicated that when the dosage of sodium carbonate was 2.0 times the stoichiometric ratio, the conversion time was 1.5 h, the conversion temperature was 75 ℃, and the amount of nitric acid was 1.8 times the stoichiometric ratio. Additionally, the dissolution time was 1.0 h, the dissolution temperature was 60 ℃, the ratio of liquid–solid was 5:1, and the separation efficiency of Pb and Hg was 98.72%. This study demonstrated the advantages of a short, simple, and environmentally friendly process for separating Pb and Hg from Cu smelting acid sludge, providing complete separation and introducing a new technology.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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