Solmers: Versatile hybrid resins for nanometric 3D printing of silica-based photonic components

Owning to their intrinsic properties, silica-based glasses are widely used in various technological fields, especially in photonics. However, high degree of flexibility is yet challenging in realization of next-generation miniaturized optical components. In this work, we develop an approach based on ‶Solmers″ hybrid resins allowing versatile two-photon polymerization 3D printing of silica glasses with 23 nm resolution, doping with Germanium and/or rare-earths elements. Other dopants such as gold nanoparticles were also incorporated for localized metallization. After 3D printing and sintering (1100–1300 °C), high optical quality glasses with low surface roughness (<0.2 nm) were obtained. Structural analyses confirmed the amorphous structure of silica glasses. Various mono- or multi-materials microstructures were successfully fabricated on fused silica substrates. Besides, this approach was extended to the functionalization of optical fibers for optical sensing applications in harsh environment (1000 °C). Compared to organic or organic-inorganic materials, these dense silica-based glasses with enhanced optical and structural properties will open new avenues for the development of emerging advanced optical components.