Sofia G. Sotiriadou, Eleftheria Ntonti, Marc J. Assael, Richard A. Perkins, Marcia L. Huber
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引用次数: 0
摘要
我们根据经过严格评估的实验数据,提出了一种新的乙烯粘度宽范围相关性。该粘度相关性在从三相点到 450 K 以及高达 195 MPa 的范围内均有效。主要数据(包括临界区)拟合的平均绝对百分比偏差为 1%,偏差为 0.2%,在压力高达 195 兆帕的气相和超临界相中,相关性的估计不确定性为 2.5%(置信度为 95%)。对于温度范围为 296 K 至 450 K 的稀释气体(压力最高为 0.1 MPa),不确定性为 0.5%。对于压力高达 5.5 兆帕的液相,估计不确定性为 5.3%。相关性包括临界增强项,该增强项仅在非常接近临界点的一个非常狭窄的区域内具有显著性。在从 279.80 K ≤ T ≤ 290.27 K 到 140.79 kg⋅m-3 ≤ ρ ≤ 293.08 kg⋅m-3 的临界点附近区域之外,该值小于 1%。
Reference Correlation of the Viscosity of Ethene from the Triple Point to 450 K and up to 195 MPa
We present a new wide-range correlation for the viscosity of ethene based on critically evaluated experimental data. The viscosity correlation is valid from the triple point to 450 K and up to 195 MPa. The average absolute percentage deviation of the fit for the primary data (including the critical region) is 1%, with a bias of 0.2%, The estimated uncertainty of the correlation in the gas and supercritical phases at pressures up to 195 MPa is 2.5% (at the 95% confidence level). For the dilute gas (pressures up to 0.1 MPa) in the temperature range 296 K to 450 K, the uncertainty is 0.5%. For the liquid phase at pressures up to 5.5 MPa the estimated uncertainty is 5.3%. The correlation includes a term for the critical enhancement that is significant only in a very narrow region very close to the critical point. It is less than 1% outside of the region around the critical point from 279.80 K ≤ T ≤ 290.27 K to 140.79 kg⋅m−3 ≤ ρ ≤ 293.08 kg⋅m−3.
期刊介绍:
International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.