I. A. Veselov, A. S. Naumov, V. I. Savinkov, S. S. Fedotov, R. O. Alekseev, E. S. Ignatieva, G. Yu. Shakhgildyan, V. N. Sigaev
{"title":"增加 Na2O 含量对 ZnO-MgO-Al2O3-SiO2 玻璃陶瓷成型体系玻璃的离子交换强化作用","authors":"I. A. Veselov, A. S. Naumov, V. I. Savinkov, S. S. Fedotov, R. O. Alekseev, E. S. Ignatieva, G. Yu. Shakhgildyan, V. N. Sigaev","doi":"10.1007/s10717-024-00651-8","DOIUrl":null,"url":null,"abstract":"<p>Zinc magnesium aluminosilicate (ZMAS) glasses were obtained with the addition of Na<sub>2</sub>O (from 1.1 to 7.0 mol.%). The influence of the Na<sub>2</sub>O content on glass forming ability and effectiveness of the ion-exchange treatment in molten KNO<sub>3</sub> was studied. The dependencies of depth and stress of subsurface layer on treatment duration were also studied along with an evaluation of the concentration shifts of alkaline cations in result of ion-exchange process. It is shown that glass Vickers hardness increases both with the Na<sub>2</sub>O content in glass and with the duration of ion-exchange. Vickers hardness of the ion-exchanged glasses with 7 mol.% of Na<sub>2</sub>O treated duration for 72 h reaches 900 <i>HV</i>. The possibility of using an ion-exchange process with glass-ceramics obtained from glasses of ZMAS system modified with sodium oxide is discussed.</p>","PeriodicalId":579,"journal":{"name":"Glass and Ceramics","volume":"81 1-2","pages":"11 - 16"},"PeriodicalIF":0.6000,"publicationDate":"2024-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Ion Exchange Strengthening of Glasses of the ZnO–MgO–Al2O3–SiO2 Glass-Ceramic-Forming System with an Increased Content of Na2O\",\"authors\":\"I. A. Veselov, A. S. Naumov, V. I. Savinkov, S. S. Fedotov, R. O. Alekseev, E. S. Ignatieva, G. Yu. Shakhgildyan, V. N. Sigaev\",\"doi\":\"10.1007/s10717-024-00651-8\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Zinc magnesium aluminosilicate (ZMAS) glasses were obtained with the addition of Na<sub>2</sub>O (from 1.1 to 7.0 mol.%). The influence of the Na<sub>2</sub>O content on glass forming ability and effectiveness of the ion-exchange treatment in molten KNO<sub>3</sub> was studied. The dependencies of depth and stress of subsurface layer on treatment duration were also studied along with an evaluation of the concentration shifts of alkaline cations in result of ion-exchange process. It is shown that glass Vickers hardness increases both with the Na<sub>2</sub>O content in glass and with the duration of ion-exchange. Vickers hardness of the ion-exchanged glasses with 7 mol.% of Na<sub>2</sub>O treated duration for 72 h reaches 900 <i>HV</i>. The possibility of using an ion-exchange process with glass-ceramics obtained from glasses of ZMAS system modified with sodium oxide is discussed.</p>\",\"PeriodicalId\":579,\"journal\":{\"name\":\"Glass and Ceramics\",\"volume\":\"81 1-2\",\"pages\":\"11 - 16\"},\"PeriodicalIF\":0.6000,\"publicationDate\":\"2024-05-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass and Ceramics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10717-024-00651-8\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass and Ceramics","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10717-024-00651-8","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
Ion Exchange Strengthening of Glasses of the ZnO–MgO–Al2O3–SiO2 Glass-Ceramic-Forming System with an Increased Content of Na2O
Zinc magnesium aluminosilicate (ZMAS) glasses were obtained with the addition of Na2O (from 1.1 to 7.0 mol.%). The influence of the Na2O content on glass forming ability and effectiveness of the ion-exchange treatment in molten KNO3 was studied. The dependencies of depth and stress of subsurface layer on treatment duration were also studied along with an evaluation of the concentration shifts of alkaline cations in result of ion-exchange process. It is shown that glass Vickers hardness increases both with the Na2O content in glass and with the duration of ion-exchange. Vickers hardness of the ion-exchanged glasses with 7 mol.% of Na2O treated duration for 72 h reaches 900 HV. The possibility of using an ion-exchange process with glass-ceramics obtained from glasses of ZMAS system modified with sodium oxide is discussed.
期刊介绍：
Glass and Ceramics reports on advances in basic and applied research and plant production techniques in glass and ceramics. The journal''s broad coverage includes developments in the areas of silicate chemistry, mineralogy and metallurgy, crystal chemistry, solid state reactions, raw materials, phase equilibria, reaction kinetics, physicochemical analysis, physics of dielectrics, and refractories, among others.
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