利用杜仲树皮介导的金纳米催化剂催化降解多种偶氮染料

IF 9 Q1 ENVIRONMENTAL SCIENCES
Hong Wan , Sania Habib , Huihong Liu , Sakil Mahmud
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引用次数: 0

摘要

在不使用任何有害物质的情况下,通过简单的杜仲树皮提取物(EUBE)还原和稳定相应的金属阳离子,合成了胶体金纳米粒子(AuNPs)。利用这些 AuNPs 作为催化剂,催化并分析了至少十种不同的偶氮化合物。研究结果表明,各种偶氮染料都具有出色的催化性能,而不论其结构的复杂程度、偶氮键的数量、侧链中是否存在各种官能团、分子量的差异、水溶性程度、染料的离子特性以及染料的特定类别(反应性或酸性)。无论这些因素如何变化,偶氮染料都能在 16 分钟内按照一阶伪动力学反应实现 90% 以上的降解。本报告系统地解释了利用 EUBE 合成 AuNPs 的机理以及逐步降解偶氮染料的过程。它标志着偶氮污染废水处理技术的进步,超越了偶氮化合物的不同类型和复杂结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Catalytic degradation of diverse azo dyes using Eucommia ulmoides bark-mediated gold nanocatalyst

In the absence of any hazardous substances, colloidal gold nanoparticles (AuNPs) were synthesized through the reduction and stabilization of corresponding metal cations by a simple Eucommia ulmoides bark extract (EUBE). Employing these AuNPs as catalysts, at least ten distinct azo compounds were catalyzed and analyzed. The findings reveal outstanding catalytic performance across a diverse range of azo dyes, regardless of structural complexity, the count of azo bonds, the presence of various functional groups in the side chains, differences in molecular weight, degrees of water solubility, ionic characteristics of the dyes, and the particular class of dyes, whether reactive or acidic. Regardless of these varieties, azo dyes achieved over 90% degradation within 16 min, following a first-order pseudo-kinetic reaction. This report systematically explains the mechanics of AuNPs synthesis using EUBE and the step-by-step azo dye degradation. It signifies an advancement in azo-contaminated wastewater treatment, transcending the varied types and structural complexities of azo compounds.

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CiteScore
15.40
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