Rosa Ma Claramunt, Concepción López, Dolores Santa María, J. Elguero
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引用次数: 0
摘要
Juliá 和 Colonna 是最早报道对映选择性有机催化反应实例的化学家之一，即相转移催化（PTC）烯烃环氧化反应。尽管已有一些关于 Juliá-Colonna 反应的综述，但没有一篇是专门针对该反应的。在用三个表格介绍了主要出版物之后，本综述分为 a) 烯烃环氧化反应；b) 其他对映选择性催化剂；c) 胡利亚-科隆纳论文；d, e) 引用 "胡利亚-科隆纳 "环氧化反应的论文，特别强调 Stanley M. Roberts 的论文。本综述总结了这些作者的论文，并报告了最相关的改进。
The Juliá-Colonna Reaction: A Phase-Transfer Catalyzed Enantioselective Olefin Epoxidation
Juliá and Colonna were one of the firsts chemists reporting examples of enantioselective organocatalyzed reactions, namely the Phase-Transfer Catalysis (PTC) olefin epoxidation. Although some reviews exist on the Juliá-Colonna reaction, none is devoted specifically to it. After an introduction reporting the main publications gathered in three tables, this review is organized into a) olefin epoxidation; b) other enantioselective catalysts; c) Juliá-Colonna papers; d, e) papers citing the "Juliá-Colonna" epoxidation with special stress on those by Stanley M. Roberts. This review summarizes the papers by these authors and reports the most relevant improvements.
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