Na2SO3 在室温下促进芳基肼的赫克偶联和均偶联

IF 3.8 3区化学 Q2 CHEMISTRY, PHYSICAL

Catalysts Pub Date : 2024-05-22 DOI:10.3390/catal14060338

Jianxiong Du, Wanhe Wang, Jinbiao Liu, Nianhua Luo

{"title":"Na2SO3 在室温下促进芳基肼的赫克偶联和均偶联","authors":"Jianxiong Du, Wanhe Wang, Jinbiao Liu, Nianhua Luo","doi":"10.3390/catal14060338","DOIUrl":null,"url":null,"abstract":"A novel protocol facilitated by Na2SO3 that enhances the efficiency of palladium-catalyzed Heck coupling and the homo-coupling reactions of arylhydrazines. This innovative method enables the effective construction of a diverse array of cinnamate derivatives and biphenyl compounds. Notably, these transformative reactions proceed smoothly at room temperature, leveraging the activation of C-N bonds. This technique not only streamlines the synthesis process but also expands our understanding and expertise in the realm of coupling reactions.","PeriodicalId":9794,"journal":{"name":"Catalysts","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature\",\"authors\":\"Jianxiong Du, Wanhe Wang, Jinbiao Liu, Nianhua Luo\",\"doi\":\"10.3390/catal14060338\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A novel protocol facilitated by Na2SO3 that enhances the efficiency of palladium-catalyzed Heck coupling and the homo-coupling reactions of arylhydrazines. This innovative method enables the effective construction of a diverse array of cinnamate derivatives and biphenyl compounds. Notably, these transformative reactions proceed smoothly at room temperature, leveraging the activation of C-N bonds. This technique not only streamlines the synthesis process but also expands our understanding and expertise in the realm of coupling reactions.\",\"PeriodicalId\":9794,\"journal\":{\"name\":\"Catalysts\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Catalysts\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.3390/catal14060338\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysts","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.3390/catal14060338","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}

引用次数: 0

摘要

一种由 Na2SO3 促成的新方案可提高钯催化的赫克偶联反应和芳基肼的均偶联反应的效率。这种创新方法能够有效地构建出一系列不同的肉桂酸酯衍生物和联苯化合物。值得注意的是，这些转化反应利用 C-N 键的活化作用在室温下顺利进行。这项技术不仅简化了合成过程，还拓展了我们对偶联反应领域的理解和专业知识。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Na2SO3-Promoted Heck Coupling and Homo-Coupling of Arylhydrazines at Room Temperature

A novel protocol facilitated by Na2SO3 that enhances the efficiency of palladium-catalyzed Heck coupling and the homo-coupling reactions of arylhydrazines. This innovative method enables the effective construction of a diverse array of cinnamate derivatives and biphenyl compounds. Notably, these transformative reactions proceed smoothly at room temperature, leveraging the activation of C-N bonds. This technique not only streamlines the synthesis process but also expands our understanding and expertise in the realm of coupling reactions.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Catalysts CHEMISTRY, PHYSICAL-

CiteScore

6.80

自引率

7.70%

发文量

1330

审稿时长

3 months

期刊介绍： Catalysts (ISSN 2073-4344) is an international open access journal of catalysts and catalyzed reactions. Catalysts publishes reviews, regular research papers (articles) and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced.