María José Muñoz-Sandoval, Yesica Vicente-Martínez, Manuel Hernández-Córdoba, Ignacio López-García
{"title":"结合磁性离子液体和磁性颗粒，利用电热原子吸收光谱法测定铅(II)和锡(IV)","authors":"María José Muñoz-Sandoval, Yesica Vicente-Martínez, Manuel Hernández-Córdoba, Ignacio López-García","doi":"10.1016/j.sab.2024.106947","DOIUrl":null,"url":null,"abstract":"<div><p>A procedure for the determination of traces of lead and tin by electrothermal atomic absorption spectrometry (ETAAS) after complexation with diethyl dithiophosphate and preconcentration by using a microextraction stage with a magnetic ionic liquid (MIL) supported by ferrite particles is presented. After complexation, the analytes are extracted into the ferrite-supported MIL, the solid particles acting as a carrier to facilitate the separation with a magnet. The analytes are released by treating with acetonitrile and the resulting liquid phase is sampled for the ETAAS measurement. The optimal experimental conditions such as pH, appropriate complexing agent, volumes and doses of all reagents used in the procedure are studied to achieve complete separation of both species. Enrichment factors of 195 and 165 and detection limits of 25 and 72 ng L<sup>−1</sup> are obtained for Pb and Sn, respectively. The reliability of the procedure is checked by analyzing six certified reference materials and applied to water samples of different origin, the results being in addition confirmed by standard additions (recoveries 97 ± 7% in all cases).</p></div>","PeriodicalId":21890,"journal":{"name":"Spectrochimica Acta Part B: Atomic Spectroscopy","volume":"216 ","pages":"Article 106947"},"PeriodicalIF":3.2000,"publicationDate":"2024-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Combination of a magnetic ionic liquid and magnetic particles for the determination of Pb(II) and Sn(IV) using electrothermal atomic absorption spectrometry\",\"authors\":\"María José Muñoz-Sandoval, Yesica Vicente-Martínez, Manuel Hernández-Córdoba, Ignacio López-García\",\"doi\":\"10.1016/j.sab.2024.106947\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A procedure for the determination of traces of lead and tin by electrothermal atomic absorption spectrometry (ETAAS) after complexation with diethyl dithiophosphate and preconcentration by using a microextraction stage with a magnetic ionic liquid (MIL) supported by ferrite particles is presented. After complexation, the analytes are extracted into the ferrite-supported MIL, the solid particles acting as a carrier to facilitate the separation with a magnet. The analytes are released by treating with acetonitrile and the resulting liquid phase is sampled for the ETAAS measurement. The optimal experimental conditions such as pH, appropriate complexing agent, volumes and doses of all reagents used in the procedure are studied to achieve complete separation of both species. Enrichment factors of 195 and 165 and detection limits of 25 and 72 ng L<sup>−1</sup> are obtained for Pb and Sn, respectively. The reliability of the procedure is checked by analyzing six certified reference materials and applied to water samples of different origin, the results being in addition confirmed by standard additions (recoveries 97 ± 7% in all cases).</p></div>\",\"PeriodicalId\":21890,\"journal\":{\"name\":\"Spectrochimica Acta Part B: Atomic Spectroscopy\",\"volume\":\"216 \",\"pages\":\"Article 106947\"},\"PeriodicalIF\":3.2000,\"publicationDate\":\"2024-05-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectrochimica Acta Part B: Atomic Spectroscopy\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0584854724000910\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"SPECTROSCOPY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta Part B: Atomic Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0584854724000910","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
Combination of a magnetic ionic liquid and magnetic particles for the determination of Pb(II) and Sn(IV) using electrothermal atomic absorption spectrometry
A procedure for the determination of traces of lead and tin by electrothermal atomic absorption spectrometry (ETAAS) after complexation with diethyl dithiophosphate and preconcentration by using a microextraction stage with a magnetic ionic liquid (MIL) supported by ferrite particles is presented. After complexation, the analytes are extracted into the ferrite-supported MIL, the solid particles acting as a carrier to facilitate the separation with a magnet. The analytes are released by treating with acetonitrile and the resulting liquid phase is sampled for the ETAAS measurement. The optimal experimental conditions such as pH, appropriate complexing agent, volumes and doses of all reagents used in the procedure are studied to achieve complete separation of both species. Enrichment factors of 195 and 165 and detection limits of 25 and 72 ng L−1 are obtained for Pb and Sn, respectively. The reliability of the procedure is checked by analyzing six certified reference materials and applied to water samples of different origin, the results being in addition confirmed by standard additions (recoveries 97 ± 7% in all cases).
期刊介绍：
Spectrochimica Acta Part B: Atomic Spectroscopy, is intended for the rapid publication of both original work and reviews in the following fields:
Atomic Emission (AES), Atomic Absorption (AAS) and Atomic Fluorescence (AFS) spectroscopy;
Mass Spectrometry (MS) for inorganic analysis covering Spark Source (SS-MS), Inductively Coupled Plasma (ICP-MS), Glow Discharge (GD-MS), and Secondary Ion Mass Spectrometry (SIMS).
Laser induced atomic spectroscopy for inorganic analysis, including non-linear optical laser spectroscopy, covering Laser Enhanced Ionization (LEI), Laser Induced Fluorescence (LIF), Resonance Ionization Spectroscopy (RIS) and Resonance Ionization Mass Spectrometry (RIMS); Laser Induced Breakdown Spectroscopy (LIBS); Cavity Ringdown Spectroscopy (CRDS), Laser Ablation Inductively Coupled Plasma Atomic Emission Spectroscopy (LA-ICP-AES) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS).
X-ray spectrometry, X-ray Optics and Microanalysis, including X-ray fluorescence spectrometry (XRF) and related techniques, in particular Total-reflection X-ray Fluorescence Spectrometry (TXRF), and Synchrotron Radiation-excited Total reflection XRF (SR-TXRF).
Manuscripts dealing with (i) fundamentals, (ii) methodology development, (iii)instrumentation, and (iv) applications, can be submitted for publication.
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