自旋交叉{[Fe(atrz)3](OTs)2}n单片：一种用于鲁棒开关材料的绿色合成方法。

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2024-05-22 DOI:10.1039/D4DT00684D

Ana Martinez-Martinez, Pablo Albacete, Mar García-Hernández, Esther Resines-Urien, David Fairen-Jimenez and José Sánchez Costa

{"title":"自旋交叉{[Fe(atrz)3](OTs)2}n单片：一种用于鲁棒开关材料的绿色合成方法。","authors":"Ana Martinez-Martinez, Pablo Albacete, Mar García-Hernández, Esther Resines-Urien, David Fairen-Jimenez and José Sánchez Costa","doi":"10.1039/D4DT00684D","DOIUrl":null,"url":null,"abstract":"This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz)3](OTs)2}n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 22","pages":" 9257-9261"},"PeriodicalIF":3.3000,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials†\",\"authors\":\"Ana Martinez-Martinez, Pablo Albacete, Mar García-Hernández, Esther Resines-Urien, David Fairen-Jimenez and José Sánchez Costa\",\"doi\":\"10.1039/D4DT00684D\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz)3](OTs)2}n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\" 22\",\"pages\":\" 9257-9261\"},\"PeriodicalIF\":3.3000,\"publicationDate\":\"2024-05-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt00684d\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt00684d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

这项研究提出了一种直接的室温合成{[Fe(atrz)3](OTs)2}n单体的方法。这种方法为操纵自旋交叉（SCO）行为提供了一种替代传统纳米粒子合成的绿色方法。与块体材料相比，整体材料在较低温度下表现出更渐进的自旋交叉转变，这与在较小颗粒系统中观察到的结果一致。值得注意的是，该合成采用了一种无溶剂和表面活性剂的方法，简化了工艺流程，并有可能减少对环境的影响，符合绿色化学的原则。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials†

查看原文本刊更多论文

Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials†

This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz)₃](OTs)₂}_n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.