可逆失活自由基聚合的数学建模

IF 8 2区工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY

Current Opinion in Chemical Engineering Pub Date : 2024-05-18 DOI:10.1016/j.coche.2024.101026

Enrique Saldívar-Guerra

{"title":"可逆失活自由基聚合的数学建模","authors":"Enrique Saldívar-Guerra","doi":"10.1016/j.coche.2024.101026","DOIUrl":null,"url":null,"abstract":"<div><p>Since its creation and diversification 30 years ago, reversible deactivation radical polymerization (RDRP) has gained tremendous relevance as a powerful and versatile set of techniques for the robust synthesis of precise polymer architectures for advanced applications. In parallel, mathematical models for the polymerization kinetics, molar mass distributions, and copolymer characteristics have rapidly developed and gained sophistication and detail. The aim of this review is to provide a summary of the most important modeling techniques used in RDRP and a brief description of the most recent literature on the subject, highlighting the most relevant issues and subjects addressed in these works.</p></div>","PeriodicalId":292,"journal":{"name":"Current Opinion in Chemical Engineering","volume":"44 ","pages":"Article 101026"},"PeriodicalIF":8.0000,"publicationDate":"2024-05-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mathematical modeling of reversible deactivation radical polymerization\",\"authors\":\"Enrique Saldívar-Guerra\",\"doi\":\"10.1016/j.coche.2024.101026\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Since its creation and diversification 30 years ago, reversible deactivation radical polymerization (RDRP) has gained tremendous relevance as a powerful and versatile set of techniques for the robust synthesis of precise polymer architectures for advanced applications. In parallel, mathematical models for the polymerization kinetics, molar mass distributions, and copolymer characteristics have rapidly developed and gained sophistication and detail. The aim of this review is to provide a summary of the most important modeling techniques used in RDRP and a brief description of the most recent literature on the subject, highlighting the most relevant issues and subjects addressed in these works.</p></div>\",\"PeriodicalId\":292,\"journal\":{\"name\":\"Current Opinion in Chemical Engineering\",\"volume\":\"44 \",\"pages\":\"Article 101026\"},\"PeriodicalIF\":8.0000,\"publicationDate\":\"2024-05-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Opinion in Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2211339824000273\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"BIOTECHNOLOGY & APPLIED MICROBIOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Opinion in Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2211339824000273","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"BIOTECHNOLOGY & APPLIED MICROBIOLOGY","Score":null,"Total":0}

引用次数: 0

摘要

可逆去活化自由基聚合技术（RDRP）自 30 年前问世并实现多样化以来，作为一套功能强大、用途广泛的技术，已在为先进应用稳健合成精密聚合物结构方面获得了巨大的现实意义。与此同时，有关聚合动力学、摩尔质量分布和共聚物特性的数学模型也得到了迅速发展，并变得越来越复杂和详细。本综述旨在概述 RDRP 中使用的最重要建模技术，并简要介绍有关该主题的最新文献，重点介绍这些著作中涉及的最相关问题和主题。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Mathematical modeling of reversible deactivation radical polymerization

Since its creation and diversification 30 years ago, reversible deactivation radical polymerization (RDRP) has gained tremendous relevance as a powerful and versatile set of techniques for the robust synthesis of precise polymer architectures for advanced applications. In parallel, mathematical models for the polymerization kinetics, molar mass distributions, and copolymer characteristics have rapidly developed and gained sophistication and detail. The aim of this review is to provide a summary of the most important modeling techniques used in RDRP and a brief description of the most recent literature on the subject, highlighting the most relevant issues and subjects addressed in these works.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Current Opinion in Chemical Engineering BIOTECHNOLOGY & APPLIED MICROBIOLOGYENGINE-ENGINEERING, CHEMICAL

CiteScore

12.80

自引率

3.00%

发文量

114

期刊介绍： Current Opinion in Chemical Engineering is devoted to bringing forth short and focused review articles written by experts on current advances in different areas of chemical engineering. Only invited review articles will be published. The goals of each review article in Current Opinion in Chemical Engineering are: 1. To acquaint the reader/researcher with the most important recent papers in the given topic. 2. To provide the reader with the views/opinions of the expert in each topic. The reviews are short (about 2500 words or 5-10 printed pages with figures) and serve as an invaluable source of information for researchers, teachers, professionals and students. The reviews also aim to stimulate exchange of ideas among experts. Themed sections: Each review will focus on particular aspects of one of the following themed sections of chemical engineering: 1. Nanotechnology 2. Energy and environmental engineering 3. Biotechnology and bioprocess engineering 4. Biological engineering (covering tissue engineering, regenerative medicine, drug delivery) 5. Separation engineering (covering membrane technologies, adsorbents, desalination, distillation etc.) 6. Materials engineering (covering biomaterials, inorganic especially ceramic materials, nanostructured materials). 7. Process systems engineering 8. Reaction engineering and catalysis.