{"title":"开发用于快速催化 CF4 分解的感应加热反应器","authors":"","doi":"10.1016/j.jiec.2024.05.020","DOIUrl":null,"url":null,"abstract":"<div><p>A novel catalytic reactor configuration based on the induction heating technique is proposed for the decomposition of CF<sub>4</sub>. To demonstrate the feasibility of this concept, a commercial catalyst and induction heating module are employed. The experimental results demonstrated that the reactor provides a fast response time (approximately 3 min) in the decomposition of CF<sub>4</sub> (roughly 100 ppm), without the requirement for insulation or preheating. In addition, introduction of the induction heating technique was found to allow precise temperature control. Furthermore, empirical guidelines for optimizing the catalyst bed are established in terms of two design factors, namely the length/diameter ratio (<span><math><mrow><mo>≥</mo></mrow></math></span> 1.48) of the catalyst bed, and 1/3 of the blending of an additional inductive heating medium in the catalyst bed. The fast response time exhibited by this system is expected to permit connection of the reactor with electric power generated by renewable energy.</p></div>","PeriodicalId":363,"journal":{"name":"Journal of Industrial and Engineering Chemistry","volume":"139 ","pages":"Pages 458-463"},"PeriodicalIF":5.9000,"publicationDate":"2024-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Development of an induction heating reactor for rapid catalytic CF4 decomposition\",\"authors\":\"\",\"doi\":\"10.1016/j.jiec.2024.05.020\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A novel catalytic reactor configuration based on the induction heating technique is proposed for the decomposition of CF<sub>4</sub>. To demonstrate the feasibility of this concept, a commercial catalyst and induction heating module are employed. The experimental results demonstrated that the reactor provides a fast response time (approximately 3 min) in the decomposition of CF<sub>4</sub> (roughly 100 ppm), without the requirement for insulation or preheating. In addition, introduction of the induction heating technique was found to allow precise temperature control. Furthermore, empirical guidelines for optimizing the catalyst bed are established in terms of two design factors, namely the length/diameter ratio (<span><math><mrow><mo>≥</mo></mrow></math></span> 1.48) of the catalyst bed, and 1/3 of the blending of an additional inductive heating medium in the catalyst bed. The fast response time exhibited by this system is expected to permit connection of the reactor with electric power generated by renewable energy.</p></div>\",\"PeriodicalId\":363,\"journal\":{\"name\":\"Journal of Industrial and Engineering Chemistry\",\"volume\":\"139 \",\"pages\":\"Pages 458-463\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2024-05-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Industrial and Engineering Chemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1226086X24003265\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Industrial and Engineering Chemistry","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1226086X24003265","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Development of an induction heating reactor for rapid catalytic CF4 decomposition
A novel catalytic reactor configuration based on the induction heating technique is proposed for the decomposition of CF4. To demonstrate the feasibility of this concept, a commercial catalyst and induction heating module are employed. The experimental results demonstrated that the reactor provides a fast response time (approximately 3 min) in the decomposition of CF4 (roughly 100 ppm), without the requirement for insulation or preheating. In addition, introduction of the induction heating technique was found to allow precise temperature control. Furthermore, empirical guidelines for optimizing the catalyst bed are established in terms of two design factors, namely the length/diameter ratio ( 1.48) of the catalyst bed, and 1/3 of the blending of an additional inductive heating medium in the catalyst bed. The fast response time exhibited by this system is expected to permit connection of the reactor with electric power generated by renewable energy.
期刊介绍:
Journal of Industrial and Engineering Chemistry is published monthly in English by the Korean Society of Industrial and Engineering Chemistry. JIEC brings together multidisciplinary interests in one journal and is to disseminate information on all aspects of research and development in industrial and engineering chemistry. Contributions in the form of research articles, short communications, notes and reviews are considered for publication. The editors welcome original contributions that have not been and are not to be published elsewhere. Instruction to authors and a manuscript submissions form are printed at the end of each issue. Bulk reprints of individual articles can be ordered. This publication is partially supported by Korea Research Foundation and the Korean Federation of Science and Technology Societies.