中东儿童玩具和婴儿产品中的双酚评估

IF 5.3 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
K. Martínez-Guijarro , B. Gevao , M. Porcelli , S. Al-Salem , Saif Uddin , M. Bahloul , H. Taqi , M. Hajeyah , D. Krishnan , S. Rajagopalan , A. Boota
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引用次数: 0

摘要

由于有证据表明双酚 A(BP-A)会从添加了它们的产品中渗出,而且在动物和人体中观察到了其干扰内分泌的作用,因此引起了科学界的高度关注。本研究分析了 BP-A 和几种相关化学物质,如双酚 AP(BP-AP)、双酚 B(BP-B)、双酚 S(BP-S)、双酚 AF(BP-AF)、双酚(BP-P)和双酚 Z(BP-Z)。本研究分析的样本中只检测到 BP-A 和 BP-S。本研究发现的 BP-A 浓度中位数(范围;平均值)为 321 纳克/克(11-200932;4893 纳克/克)。分析方法是将 0.1 克经低温研磨的等分样品放入甲醇中超声处理,然后进行 UPLC-MS/MS 测定。在一些标明不含 BP-A 的产品中发现了高浓度的 BP-A,如哺乳瓶,从儿童接触的角度来看,这些产品尤其有问题。这项研究首次提出了中东地区商业化儿童玩具和婴儿产品中可靠的双酚含量。不过,有必要继续监测这些化合物,尤其是低成本玩具和所谓的不含 BP-A 的产品中的化合物,因为这些产品似乎含有大量目标污染物,可能会对该地区的婴幼儿造成接触风险。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Assessment of bisphenols in children's toy and baby products in the Middle East

A major concern from the scientific community has been raised since evidence of Bisphenol A (BP-A) can leach out from the products where they are incorporated as well as its endocrine disrupting effects observed in animals and humans. BP-A and several related chemicals such as Bisphenol AP (BP-AP), Bisphenol B (BP–B), Bisphenol S (BP–S), Bisphenol AF (BP-AF), Bisphenol (BP–P), Bisphenol Z (BP-Z) were analyzed in this study. BP-A and BP-S were the only bisphenols detected in the samples analyzed in this study. The median (range; mean) concentrations of BP-A found in this study was 321 ng/g (11–200932; 4893 ng/g). The analysis was carried out by sonicating 0.1 g of a cryo-milled sample aliquot in methanol followed by UPLC-MS/MS determination. High concentrations of BP-A were found in several products labeled as BP-A free such as nursing bottles which are particularly problematic from the children's exposure point of view. This study presents the first reliable bisphenols in children's toys and baby products commercialized in the Middle East. There is, however, a need to continue monitoring these compounds, especially in low-cost toys, and the so-called BP-A-free products, which appear to have high levels of target contaminants and can pose an exposure risk for infants and children in the region.

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来源期刊
Emerging Contaminants
Emerging Contaminants Medicine-Public Health, Environmental and Occupational Health
CiteScore
10.00
自引率
6.70%
发文量
35
审稿时长
44 days
期刊介绍: Emerging Contaminants is an outlet for world-leading research addressing problems associated with environmental contamination caused by emerging contaminants and their solutions. Emerging contaminants are defined as chemicals that are not currently (or have been only recently) regulated and about which there exist concerns regarding their impact on human or ecological health. Examples of emerging contaminants include disinfection by-products, pharmaceutical and personal care products, persistent organic chemicals, and mercury etc. as well as their degradation products. We encourage papers addressing science that facilitates greater understanding of the nature, extent, and impacts of the presence of emerging contaminants in the environment; technology that exploits original principles to reduce and control their environmental presence; as well as the development, implementation and efficacy of national and international policies to protect human health and the environment from emerging contaminants.
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