Michele Arienzo , Sergio Bravi , Maria Toscanesi , Carlo Donadio , Giuseppe De Simone , Corrado Stanislao , Luciano Ferrara , Vincenzo Allocca , Antonella Giarra , Marco Trifuoggi
{"title":"意大利南部帕提亚湖湿地表层沉积物中的重金属与环境风险","authors":"Michele Arienzo , Sergio Bravi , Maria Toscanesi , Carlo Donadio , Giuseppe De Simone , Corrado Stanislao , Luciano Ferrara , Vincenzo Allocca , Antonella Giarra , Marco Trifuoggi","doi":"10.1016/j.gexplo.2024.107490","DOIUrl":null,"url":null,"abstract":"<div><p>The study investigated the presence of heavy metals in the surface sediments of one of the most important wetlands in south Italy, Lake Patria, and the related environmental risk. Surface sediments were analyzed for particle size and shape, total organic carbon and As, Cd, Cr, Cu, Fe, Hg, Ni, Pb and Zn levels. Mean total organic carbon was high, 3.1 %, with a peak of 5.9 % near the input of freshwater channel whereas sediments appeared to be mainly composed of sand and/or gravel and significantly polluted by metals especially Cr, Cu and Zn. Data from heavy metals spatial distribution, Pearson correlation, principal component analysis and geochemical indices suggested dominant anthropogenic source for most metals. Mean I<sub>geo</sub> values of Cr, Cu and Ni were in the range of 4.6–7.3 of strongly polluted class while their relative mean enrichment factors were largely exceeding the threshold of the anthropic pollution, 1.5. A very high pollution situation was also outlined when considering the Cf indices, with Cr, Cu and Ni possessing mean values from an order of magnitude of ten to hundred times higher the very high polluted class, 6 ≤ Cf. On the overall, the integrated indices of modified contamination degree, pollution load and ecological risk revealed a serious pollution scenario. The mean comprehensive ecological hazard index was fivefold the most critical limit, ≥600, in almost all the lagoon and especially in the locations close to channel.</p></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":null,"pages":null},"PeriodicalIF":3.4000,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Heavy metals in surface sediments of Lake Patria wetland, southern Italy, and environmental risk\",\"authors\":\"Michele Arienzo , Sergio Bravi , Maria Toscanesi , Carlo Donadio , Giuseppe De Simone , Corrado Stanislao , Luciano Ferrara , Vincenzo Allocca , Antonella Giarra , Marco Trifuoggi\",\"doi\":\"10.1016/j.gexplo.2024.107490\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The study investigated the presence of heavy metals in the surface sediments of one of the most important wetlands in south Italy, Lake Patria, and the related environmental risk. Surface sediments were analyzed for particle size and shape, total organic carbon and As, Cd, Cr, Cu, Fe, Hg, Ni, Pb and Zn levels. Mean total organic carbon was high, 3.1 %, with a peak of 5.9 % near the input of freshwater channel whereas sediments appeared to be mainly composed of sand and/or gravel and significantly polluted by metals especially Cr, Cu and Zn. Data from heavy metals spatial distribution, Pearson correlation, principal component analysis and geochemical indices suggested dominant anthropogenic source for most metals. Mean I<sub>geo</sub> values of Cr, Cu and Ni were in the range of 4.6–7.3 of strongly polluted class while their relative mean enrichment factors were largely exceeding the threshold of the anthropic pollution, 1.5. A very high pollution situation was also outlined when considering the Cf indices, with Cr, Cu and Ni possessing mean values from an order of magnitude of ten to hundred times higher the very high polluted class, 6 ≤ Cf. On the overall, the integrated indices of modified contamination degree, pollution load and ecological risk revealed a serious pollution scenario. The mean comprehensive ecological hazard index was fivefold the most critical limit, ≥600, in almost all the lagoon and especially in the locations close to channel.</p></div>\",\"PeriodicalId\":16336,\"journal\":{\"name\":\"Journal of Geochemical Exploration\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2024-05-03\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Geochemical Exploration\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0375674224001067\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375674224001067","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Heavy metals in surface sediments of Lake Patria wetland, southern Italy, and environmental risk
The study investigated the presence of heavy metals in the surface sediments of one of the most important wetlands in south Italy, Lake Patria, and the related environmental risk. Surface sediments were analyzed for particle size and shape, total organic carbon and As, Cd, Cr, Cu, Fe, Hg, Ni, Pb and Zn levels. Mean total organic carbon was high, 3.1 %, with a peak of 5.9 % near the input of freshwater channel whereas sediments appeared to be mainly composed of sand and/or gravel and significantly polluted by metals especially Cr, Cu and Zn. Data from heavy metals spatial distribution, Pearson correlation, principal component analysis and geochemical indices suggested dominant anthropogenic source for most metals. Mean Igeo values of Cr, Cu and Ni were in the range of 4.6–7.3 of strongly polluted class while their relative mean enrichment factors were largely exceeding the threshold of the anthropic pollution, 1.5. A very high pollution situation was also outlined when considering the Cf indices, with Cr, Cu and Ni possessing mean values from an order of magnitude of ten to hundred times higher the very high polluted class, 6 ≤ Cf. On the overall, the integrated indices of modified contamination degree, pollution load and ecological risk revealed a serious pollution scenario. The mean comprehensive ecological hazard index was fivefold the most critical limit, ≥600, in almost all the lagoon and especially in the locations close to channel.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.