{"title":"三维多孔双金属金属有机框架/明胶气凝胶:一种易于回收的过硫酸盐活化剂,用于高效、连续地去除有机染料","authors":"Wenlong Xiang , Xian Zhang , Rou Xiao , Yanhui Zhang","doi":"10.1016/j.cjche.2024.04.007","DOIUrl":null,"url":null,"abstract":"<div><p>As promising catalysts for the degradation of organic pollutants, metal–organic frameworks (MOFs) often face limitations due to the particle agglomeration and challenging recovery in liquid-catalysis application, stemming from their powdery nature. Engineering macroscopic structures from pulverous MOF is thus of great importance for broadening their practical applications. In this study, three-dimensional porous MOF aerogel catalysts were successfully fabricated for degrading organic dyes by activating peroxymonosulfate (PMS). MOF/gelatin aerogel (MOF/GA) catalysts were prepared by directly integrating bimetallic FeCo-BDC with gelatin solutions, followed by freeze-drying and low-temperature calcination. The FeCo-BDC-0.15/GA/PMS system exhibited remarkable performance in degrading various organic dyes, eliminating 99.2% of rhodamine B within a mere 5 min. Compared to the GA/PMS system, there was over a 300-fold increase in the reaction rate constant. Remarkably, high removal efficiency was maintained across varying conditions, including different solution pH, co-existing inorganic anions, and natural water matrices. Radical trapping experiments and electron paramagnetic resonance analysis revealed that the degradation involved radical (<span><math><mrow><msubsup><mtext>SO</mtext><mn>4</mn><mo>−</mo></msubsup><mo>·</mo></mrow></math></span>) and non-radical routes (<sup>1</sup>O<sub>2</sub>), of which <sup>1</sup>O<sub>2</sub> was dominant. Furthermore, even after a continuous 400-min reaction in a fixed-bed reactor at a liquid hourly space velocity of 27 h<sup>−1</sup>, the FeCo-BDC/GA composite sustained a degradation efficiency exceeding 98.7%. This work presents highly active MOF-gelatin aerogels for dye degradation and expands the potential for their large-scale, continuous treatment application in organic dye wastewater management.</p></div>","PeriodicalId":9966,"journal":{"name":"Chinese Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":3.7000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Three-dimensional porous bimetallic metal–organic framework/gelatin aerogels: A readily recyclable peroxymonosulfate activator for efficient and continuous organic dye removal\",\"authors\":\"Wenlong Xiang , Xian Zhang , Rou Xiao , Yanhui Zhang\",\"doi\":\"10.1016/j.cjche.2024.04.007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>As promising catalysts for the degradation of organic pollutants, metal–organic frameworks (MOFs) often face limitations due to the particle agglomeration and challenging recovery in liquid-catalysis application, stemming from their powdery nature. Engineering macroscopic structures from pulverous MOF is thus of great importance for broadening their practical applications. In this study, three-dimensional porous MOF aerogel catalysts were successfully fabricated for degrading organic dyes by activating peroxymonosulfate (PMS). MOF/gelatin aerogel (MOF/GA) catalysts were prepared by directly integrating bimetallic FeCo-BDC with gelatin solutions, followed by freeze-drying and low-temperature calcination. The FeCo-BDC-0.15/GA/PMS system exhibited remarkable performance in degrading various organic dyes, eliminating 99.2% of rhodamine B within a mere 5 min. Compared to the GA/PMS system, there was over a 300-fold increase in the reaction rate constant. Remarkably, high removal efficiency was maintained across varying conditions, including different solution pH, co-existing inorganic anions, and natural water matrices. Radical trapping experiments and electron paramagnetic resonance analysis revealed that the degradation involved radical (<span><math><mrow><msubsup><mtext>SO</mtext><mn>4</mn><mo>−</mo></msubsup><mo>·</mo></mrow></math></span>) and non-radical routes (<sup>1</sup>O<sub>2</sub>), of which <sup>1</sup>O<sub>2</sub> was dominant. Furthermore, even after a continuous 400-min reaction in a fixed-bed reactor at a liquid hourly space velocity of 27 h<sup>−1</sup>, the FeCo-BDC/GA composite sustained a degradation efficiency exceeding 98.7%. This work presents highly active MOF-gelatin aerogels for dye degradation and expands the potential for their large-scale, continuous treatment application in organic dye wastewater management.</p></div>\",\"PeriodicalId\":9966,\"journal\":{\"name\":\"Chinese Journal of Chemical Engineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chinese Journal of Chemical Engineering\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1004954124001204\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chinese Journal of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1004954124001204","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Three-dimensional porous bimetallic metal–organic framework/gelatin aerogels: A readily recyclable peroxymonosulfate activator for efficient and continuous organic dye removal
As promising catalysts for the degradation of organic pollutants, metal–organic frameworks (MOFs) often face limitations due to the particle agglomeration and challenging recovery in liquid-catalysis application, stemming from their powdery nature. Engineering macroscopic structures from pulverous MOF is thus of great importance for broadening their practical applications. In this study, three-dimensional porous MOF aerogel catalysts were successfully fabricated for degrading organic dyes by activating peroxymonosulfate (PMS). MOF/gelatin aerogel (MOF/GA) catalysts were prepared by directly integrating bimetallic FeCo-BDC with gelatin solutions, followed by freeze-drying and low-temperature calcination. The FeCo-BDC-0.15/GA/PMS system exhibited remarkable performance in degrading various organic dyes, eliminating 99.2% of rhodamine B within a mere 5 min. Compared to the GA/PMS system, there was over a 300-fold increase in the reaction rate constant. Remarkably, high removal efficiency was maintained across varying conditions, including different solution pH, co-existing inorganic anions, and natural water matrices. Radical trapping experiments and electron paramagnetic resonance analysis revealed that the degradation involved radical () and non-radical routes (1O2), of which 1O2 was dominant. Furthermore, even after a continuous 400-min reaction in a fixed-bed reactor at a liquid hourly space velocity of 27 h−1, the FeCo-BDC/GA composite sustained a degradation efficiency exceeding 98.7%. This work presents highly active MOF-gelatin aerogels for dye degradation and expands the potential for their large-scale, continuous treatment application in organic dye wastewater management.
期刊介绍:
The Chinese Journal of Chemical Engineering (Monthly, started in 1982) is the official journal of the Chemical Industry and Engineering Society of China and published by the Chemical Industry Press Co. Ltd. The aim of the journal is to develop the international exchange of scientific and technical information in the field of chemical engineering. It publishes original research papers that cover the major advancements and achievements in chemical engineering in China as well as some articles from overseas contributors.
The topics of journal include chemical engineering, chemical technology, biochemical engineering, energy and environmental engineering and other relevant fields. Papers are published on the basis of their relevance to theoretical research, practical application or potential uses in the industry as Research Papers, Communications, Reviews and Perspectives. Prominent domestic and overseas chemical experts and scholars have been invited to form an International Advisory Board and the Editorial Committee. It enjoys recognition among Chinese academia and industry as a reliable source of information of what is going on in chemical engineering research, both domestic and abroad.