高量子产率绿色发光碳点应用于光电转换薄膜,防止蓝光损伤

Longchuang Li, Yuan Li, Tao Zhang, Yan Li, Zijian Li, Hong Bi
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引用次数: 0

摘要

高能蓝光会穿透晶状体进入视网膜,可能导致视网膜色素上皮细胞萎缩甚至死亡,因此对健康极为不利。为了防止高能蓝光对人体健康造成危害,本文报道了一种专门用于阻挡高能蓝光的光电转换薄膜的制备方法,该薄膜由分散在聚乙烯醇(PVA)基质中的具有高光量子产率(PLQY = 95%)的绿色发射碳点(G-CD)组成。值得注意的是,这种薄膜(命名为 G-CDs@PVA)不仅能将入射的短波长激光转化为长波长荧光,还能表现出浓度依赖性(0、10、20 和 30 wt.%)的蓝光阻隔率和绿光发射强度。随着薄膜中 G-CDs 浓度的增加,薄膜的蓝光阻隔率和绿色发射的最大强度也随之增加。当 G-CDs 的浓度达到 30 wt.% 时,G-CDs@PVA 的蓝光阻隔率高达 97%。此外,还将 G-CDs@PVA 薄膜附着在蓝光发光二极管(LED)芯片上,以探索其在阻隔蓝光伤害领域的实际应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Green-Emissive Carbon Dots with a High Quantum Yield Applied for Photoconversion Film to Prevent from Blue Light Damage

Green-Emissive Carbon Dots with a High Quantum Yield Applied for Photoconversion Film to Prevent from Blue Light Damage

High-energy blue light is highly detrimental to health as it can penetrate the lens into the retina, potentially causing atrophy or even death of retinal pigment epithelial cells. To prevent the harmful effects of high-energy blue light on our health, here the preparation of a photoconversion film specifically designed to block high-energy blue light is reported, which is composed of green-emissive carbon dots (G-CDs) with a high photoluminescence quantum yield (PLQY = 95%) dispersed in polyvinyl alcohol (PVA) matrix. Notably, such a film (named as G-CDs@PVA) not only converts an incident laser light with a short wavelength into a fluorescence with a longer wavelength, but also exhibits concentration-dependent (0, 10, 20, and 30 wt.%) blue light barrier rate and green-emissive intensity. With the increase of the concentration of G-CDs in the film, the blue light barrier rate of the film as well as the maximum intensity of the green emission are also increased. When the concentration of G-CDs reaches 30 wt.%, the blue light barrier rate of G-CDs@PVA achieves up to 97%. Furthermore, G-CDs@PVA film is attached to a blue light-emitting diode (LED) chip to explore its practical application in the field of blocking blue light damage.

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