利用二茂锆(III)进行光诱导碳自由基生成

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2024-05-15 DOI:10.1093/chemle/upae095

Eisuke Ota, Kazuhiro Aida, Junichiro Yamaguchi

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引用次数: 0

摘要

随着光氧化还原化学的最新进展，出现了多种生成碳自由基的方法。本综述重点介绍了利用二茂锆(III)生成自由基的最新方法，二茂锆(III)是一种在有机合成中很少使用的物质。其中特别值得关注的是采用可见光照射的方法，这种方法可诱导烷基锆的 C-Zr 键均解，或激活光氧化催化剂以还原二茂锆(IV)。

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Harnessing Zirconocene (III) for Photoinduced Carbon Radical Generation

With recent advances in photoredox chemistry, a variety of methods for generating carbon radicals have emerged. This review highlights recent approaches for radical generation utilizing zirconocene(III), a species infrequently employed in organic syntheses. Of particular interest are methods employing visible light irradiation, which induce C–Zr bond homolysis of alkyl zirconium species or activate a photoredox catalyst to reduce zirconocene(IV).

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.