{"title":"原位构建富含 N 的氮化碳 (C3N5)/ 磷酸银 (Ag3PO4) S 型异质结,用于高效光催化去除左氧氟沙星抗生素和 RhB","authors":"Xiaodong Liu, Yuanfei Li, Huanli Wang, Jiayuan Liu, Jingchuan Fu, Jia Liu, Shijie Li","doi":"10.1007/s42823-024-00741-1","DOIUrl":null,"url":null,"abstract":"<div><p>Building step-scheme (S-scheme) heterojunctions has recently emerged as a highly effective approach for developing superior photocatalysts for water purification. Herein, a C<sub>3</sub>N<sub>5</sub>/Ag<sub>3</sub>PO<sub>4</sub> (CA) S-scheme heterojunction was prepared by in situ growth of Ag<sub>3</sub>PO<sub>4</sub> nanoparticles on 2D C<sub>3</sub>N<sub>5</sub> nanosheets. Notably, under visible-light irridiation, CA exhibited significantly higher activity in the photodegradation of LEVO, which is about 28.38, 2.41, and 2.14 times higher than the rates for C<sub>3</sub>N<sub>5</sub>, Ag<sub>3</sub>PO<sub>4</sub>, and the mixture, respectively. Based on the radical scavenging experiments, the mechanism for enhanced photocatalytic performance has been analyzed, is attributed to improved interfacial charge separation, the elevated redox potential of photon-generated electrons and holes, and the increased generation of active species resulting from the S-scheme transfer of photoinduced carriers. Additionally, CA demonstrates greater stability than either C<sub>3</sub>N<sub>5</sub> or Ag<sub>3</sub>PO<sub>4</sub> alone in the photo-oxidation of LEVO and the photodegradation of RhB. In essence, this study not only deepens our comprehension of the photocatalytic mechanism of CA, but also pioneers a novel concept for the development of highly effective and stable S-type heterojunction photocatalysts.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":506,"journal":{"name":"Carbon Letters","volume":"34 7","pages":"1995 - 2011"},"PeriodicalIF":5.5000,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"In situ construction of N-rich carbon nitride (C3N5)/silver phosphate (Ag3PO4) S-scheme heterojunctions for the efficient photocatalytic removal of levofloxacin antibiotic and RhB\",\"authors\":\"Xiaodong Liu, Yuanfei Li, Huanli Wang, Jiayuan Liu, Jingchuan Fu, Jia Liu, Shijie Li\",\"doi\":\"10.1007/s42823-024-00741-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Building step-scheme (S-scheme) heterojunctions has recently emerged as a highly effective approach for developing superior photocatalysts for water purification. Herein, a C<sub>3</sub>N<sub>5</sub>/Ag<sub>3</sub>PO<sub>4</sub> (CA) S-scheme heterojunction was prepared by in situ growth of Ag<sub>3</sub>PO<sub>4</sub> nanoparticles on 2D C<sub>3</sub>N<sub>5</sub> nanosheets. Notably, under visible-light irridiation, CA exhibited significantly higher activity in the photodegradation of LEVO, which is about 28.38, 2.41, and 2.14 times higher than the rates for C<sub>3</sub>N<sub>5</sub>, Ag<sub>3</sub>PO<sub>4</sub>, and the mixture, respectively. Based on the radical scavenging experiments, the mechanism for enhanced photocatalytic performance has been analyzed, is attributed to improved interfacial charge separation, the elevated redox potential of photon-generated electrons and holes, and the increased generation of active species resulting from the S-scheme transfer of photoinduced carriers. Additionally, CA demonstrates greater stability than either C<sub>3</sub>N<sub>5</sub> or Ag<sub>3</sub>PO<sub>4</sub> alone in the photo-oxidation of LEVO and the photodegradation of RhB. 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引用次数: 0
摘要
建立阶梯式(S-scheme)异质结最近已成为开发用于水净化的优质光催化剂的一种非常有效的方法。本文通过在二维 C3N5 纳米片上原位生长 Ag3PO4 纳米颗粒,制备了 C3N5/Ag3PO4 (CA) S 型异质结。值得注意的是,在可见光照射下,CA 对 LEVO 的光降解活性明显更高,分别是 C3N5、Ag3PO4 和混合物的 28.38 倍、2.41 倍和 2.14 倍。根据自由基清除实验,分析了光催化性能增强的机理,认为是由于改善了界面电荷分离、光子产生的电子和空穴的氧化还原电位升高,以及光诱导载流子的 S 型转移导致活性物种的生成增加。此外,在 LEVO 的光氧化和 RhB 的光降解过程中,CA 比单独使用 C3N5 或 Ag3PO4 表现出更高的稳定性。从本质上讲,这项研究不仅加深了我们对 CA 光催化机理的理解,而且为开发高效稳定的 S 型异质结光催化剂开创了一个新概念。
In situ construction of N-rich carbon nitride (C3N5)/silver phosphate (Ag3PO4) S-scheme heterojunctions for the efficient photocatalytic removal of levofloxacin antibiotic and RhB
Building step-scheme (S-scheme) heterojunctions has recently emerged as a highly effective approach for developing superior photocatalysts for water purification. Herein, a C3N5/Ag3PO4 (CA) S-scheme heterojunction was prepared by in situ growth of Ag3PO4 nanoparticles on 2D C3N5 nanosheets. Notably, under visible-light irridiation, CA exhibited significantly higher activity in the photodegradation of LEVO, which is about 28.38, 2.41, and 2.14 times higher than the rates for C3N5, Ag3PO4, and the mixture, respectively. Based on the radical scavenging experiments, the mechanism for enhanced photocatalytic performance has been analyzed, is attributed to improved interfacial charge separation, the elevated redox potential of photon-generated electrons and holes, and the increased generation of active species resulting from the S-scheme transfer of photoinduced carriers. Additionally, CA demonstrates greater stability than either C3N5 or Ag3PO4 alone in the photo-oxidation of LEVO and the photodegradation of RhB. In essence, this study not only deepens our comprehension of the photocatalytic mechanism of CA, but also pioneers a novel concept for the development of highly effective and stable S-type heterojunction photocatalysts.
期刊介绍:
Carbon Letters aims to be a comprehensive journal with complete coverage of carbon materials and carbon-rich molecules. These materials range from, but are not limited to, diamond and graphite through chars, semicokes, mesophase substances, carbon fibers, carbon nanotubes, graphenes, carbon blacks, activated carbons, pyrolytic carbons, glass-like carbons, etc. Papers on the secondary production of new carbon and composite materials from the above mentioned various carbons are within the scope of the journal. Papers on organic substances, including coals, will be considered only if the research has close relation to the resulting carbon materials. Carbon Letters also seeks to keep abreast of new developments in their specialist fields and to unite in finding alternative energy solutions to current issues such as the greenhouse effect and the depletion of the ozone layer. The renewable energy basics, energy storage and conversion, solar energy, wind energy, water energy, nuclear energy, biomass energy, hydrogen production technology, and other clean energy technologies are also within the scope of the journal. Carbon Letters invites original reports of fundamental research in all branches of the theory and practice of carbon science and technology.