O. V. Pikalov, N. V. Demeneva, I. I. Zverkova, S. I. Bredikhin
{"title":"用于保护固体氧化物电解槽中使用的 Crofer 22 APU 钢集流体的镍钴扩散涂层","authors":"O. V. Pikalov, N. V. Demeneva, I. I. Zverkova, S. I. Bredikhin","doi":"10.1134/s1023193524030108","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>The evolution of the microstructure and the composition of Ni–Co coatings used for protecting the current collectors of stainless steel Crofer 22 APU from oxidation is studied in the operation mode of the anode chamber of a solid-oxide electrolyzer cell (SOEC). It is shown that the interdiffusion of steel and coating components and the redox reactions that proceed under the coating in the SOEC operation mode block the chromium diffusion to the current collector surface. The exploitation of the anodic chamber in the air atmosphere changes the Ni–Cr metal composition of the protective coating to a mixture of highly conductive oxides (Fe,Ni,Co)<sub>3</sub>O<sub>4</sub> and (Ni,Co)O, thus changing the form of the time dependence of the surface resistivity of the junction current collector/anode. At the same time, the 7000 h tests revealed sufficiently low values, viz., ~17 mΩ cm<sup>2</sup>, which means that these coatings can be used for the anti-oxidation protection of the stainless-steel current collectors in SOECs.</p>","PeriodicalId":760,"journal":{"name":"Russian Journal of Electrochemistry","volume":null,"pages":null},"PeriodicalIF":1.1000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Diffusion Coatings Nickel–Cobalt for Protecting the Current Collectors of Crofer 22 APU Steel Used in Solid Oxide Electrolyzer Cells\",\"authors\":\"O. V. Pikalov, N. V. Demeneva, I. I. Zverkova, S. I. Bredikhin\",\"doi\":\"10.1134/s1023193524030108\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>The evolution of the microstructure and the composition of Ni–Co coatings used for protecting the current collectors of stainless steel Crofer 22 APU from oxidation is studied in the operation mode of the anode chamber of a solid-oxide electrolyzer cell (SOEC). It is shown that the interdiffusion of steel and coating components and the redox reactions that proceed under the coating in the SOEC operation mode block the chromium diffusion to the current collector surface. The exploitation of the anodic chamber in the air atmosphere changes the Ni–Cr metal composition of the protective coating to a mixture of highly conductive oxides (Fe,Ni,Co)<sub>3</sub>O<sub>4</sub> and (Ni,Co)O, thus changing the form of the time dependence of the surface resistivity of the junction current collector/anode. At the same time, the 7000 h tests revealed sufficiently low values, viz., ~17 mΩ cm<sup>2</sup>, which means that these coatings can be used for the anti-oxidation protection of the stainless-steel current collectors in SOECs.</p>\",\"PeriodicalId\":760,\"journal\":{\"name\":\"Russian Journal of Electrochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Electrochemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1134/s1023193524030108\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Electrochemistry","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1134/s1023193524030108","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Diffusion Coatings Nickel–Cobalt for Protecting the Current Collectors of Crofer 22 APU Steel Used in Solid Oxide Electrolyzer Cells
Abstract
The evolution of the microstructure and the composition of Ni–Co coatings used for protecting the current collectors of stainless steel Crofer 22 APU from oxidation is studied in the operation mode of the anode chamber of a solid-oxide electrolyzer cell (SOEC). It is shown that the interdiffusion of steel and coating components and the redox reactions that proceed under the coating in the SOEC operation mode block the chromium diffusion to the current collector surface. The exploitation of the anodic chamber in the air atmosphere changes the Ni–Cr metal composition of the protective coating to a mixture of highly conductive oxides (Fe,Ni,Co)3O4 and (Ni,Co)O, thus changing the form of the time dependence of the surface resistivity of the junction current collector/anode. At the same time, the 7000 h tests revealed sufficiently low values, viz., ~17 mΩ cm2, which means that these coatings can be used for the anti-oxidation protection of the stainless-steel current collectors in SOECs.
期刊介绍：
Russian Journal of Electrochemistry is a journal that covers all aspects of research in modern electrochemistry. The journal welcomes submissions in English or Russian regardless of country and nationality of authors.
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